SATHEE: Some Basic Principles Of Organic Chemistry Question 371

Some Basic Principles Of Organic Chemistry Question 371

Question: Which will give chiral molecule [DPMT 2005]

Options:

A) $C H_{3} C O C l \overset{L i A l H_{4}}{\to}$

B) $C_{2} H_{5} C H O \underset{H^{+} / H_{2} O}{\overset{C H_{3} M g B r}{\to}},$

C) ${(C H_{3})}_{2} C H C_{2} H_{5} \overset{C u}{\to}$

D) $\begin{matrix} H \\ C H_{3} \end{matrix} C = C \begin{matrix} C H_{3} \\ C H_{3} \end{matrix} \overset{C l_{2}}{\to}$

Show Answer

Answer:

Correct Answer: B

Solution:

$C_{2} H_{5} C H O \underset{H^{+} / H_{2} O}{\overset{C H_{3} M g B r}{\to}} \underset{C H_{3}}{\underset{|}{\overset{, H}{\overset{|}{C_{2} H_{5} - C^{*} - O H},},},},$

$C^{*}$ -chiral carbon as all the four valencies are attached with different substituents or groups.

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Some Basic Principles Of Organic Chemistry Question 371

Question: Which will give chiral molecule [DPMT 2005]

Options:

Answer:

Solution:

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