Some Basic Principles Of Organic Chemistry Question 272

Question: Which of the following cannot undergo nucleophilic substitution under ordinary conditions [J & K 2005]

Options:

A) Chlorobenzene

B) tert-butylchloride

C) Isopropyl chloride

D) None of these

Show Answer

Answer:

Correct Answer: D

Solution:

All the given species undergo nucleophilic substitution reaction.

This reactivity can be explained in terms of the nature of $ C-X $ bond which is highly polarised covalent bond due to large difference in the electronegativities of carbon and halogen atoms.

$ -\overset{{{\delta }^{+}}}{\mathop{C}},-\overset{{{\delta }^{-}}}{\mathop{X}}, $



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