Some Basic Principles Of Organic Chemistry Question 233

Question: Consider the following reactions at $ 1000{}^\circ C $ . $ Zn(s)+\frac{1}{2}O_2(g)\to ZnO(g);,\Delta G^{o}=-360,kJ/mol $ $ C(s)+\frac{1}{2}O_2(g)\to CO(g);,\Delta G^{o}=-400,kJ/mol $ Choose the correct statement at $ 1000{}^\circ C $ .

Options:

A) Zinc can be oxidized by CO

B) Zinc oxide can be reduced by C

C) Both statements [a] and [b] are true

D) Both statements [a] and [b] are false

Show Answer

Answer:

Correct Answer: B

Solution:

Carbon is the suitable reducing agent for zinc oxide at $ 1000{}^\circ C $ as $ \Delta G^o_{CO}-\Delta G^o_{ZnO} $ is negative.

$ \Delta G^o_{CO}-\Delta G^o_{ZnO}=-,400-(-360)=-,40 $ KJ/mol.



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