Some Basic Principles Of Organic Chemistry Question 204

Question: Which is the decreasing order of stability [IIT-JEE (Screening) 1993] (i) $ CH_3-\overset{+}{\mathop{C}},H-CH_3 $ (ii) $ CH_3-\overset{+}{\mathop{C}},H-O-CH_3 $ (iii) $ CH_3-\overset{+}{\mathop{C}},H-CO-CH_3 $

Options:

A) $ (i)<(ii)<(iii) $

B) $ (i)>(ii)>(iii) $

C) $ (iii)>(ii)>(i) $

D) $ (ii)>(iii)>(i) $

Show Answer

Answer:

Correct Answer: B

Solution:

$ CH_3-\overset{,+}{\mathop{\underset{CH_3}{\mathop{\underset{|,}{\mathop{CH}},}},}}>CH_3-\underset{OCH_3}{\mathop{\underset{|,}{\overset{,+}{\mathop{CH}}},}},>CH_3-\underset{COCH_3}{\mathop{\underset{|}{\mathop{\overset{+}{\mathop{CH}},}},}}, $



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