Some Basic Principles Of Organic Chemistry Question 201

Question: Reactivity towards nucleophilic addition reaction of (I) HCHO, (II) $ CH_3CHO $ , (III) $ CH_3COCH_3 $ is [Orissa JEE 2004]

Options:

A) II > III > I

B) III > II > I

C) I > II > III

D) I > II < III

Show Answer

Answer:

Correct Answer: C

Solution:

Carbonyl carbon become more reactive toward nucleophilic addition by increasing the +I effect of alkyl group so the reactivity order is as $ \underset{I}{\mathop{HCHO}},>\underset{II}{\mathop{CH_3CHO}},>\underset{IIII}{\mathop{CH_3COCH_3}}, $



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