Some Basic Principles Of Organic Chemistry Question 186

Question: Total number of isomers of $ C_6H_{14} $ are [IIT-JEE 1987; DPMT 1983; CPMT 1991; MNR 1990; MP PET 1995; UPSEAT 2001]

Options:

A) 4

B) 5

C) 6

D) 7

Show Answer

Answer:

Correct Answer: B

Solution:

1.$ \underset{n-hexane}{\mathop{CH_3-CH_2-CH_2-CH_2-CH_2-CH_3}}, $

2.$ \underset{2-methyl,pentane}{\mathop{CH_3-\underset{CH_3}{\mathop{\underset{|,}{\mathop{CH-}},}},CH_2-CH_2-CH_3}}, $

3.$ \underset{3-methyl,pentane}{\mathop{CH_3-CH_2-\underset{,CH_3}{\mathop{\underset{|}{\mathop{CH}},}},-CH_2-CH_3}}, $

4.$ \underset{\text{2,3}-Dimethyl,butane}{\mathop{CH_3-\underset{CH_3}{\mathop{\underset{|,}{\mathop{CH-}},}},\underset{CH_3}{\mathop{\underset{|,}{\mathop{CH-}},}},CH_3}}, $

5.$ \underset{3-methyl,pentane}{\mathop{CH_3-CH_2-\underset{,CH_3}{\mathop{\underset{|}{\mathop{CH}},}},-CH_2-CH_3}}, $



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