Some Basic Principles Of Organic Chemistry Question 173

Question: Which one of the following species is most stable [IIT-JEE 1995]

Options:

A) $ p-O_2N-C_6H_4-\overset{+}{\mathop{C}},H_2 $

B) $ p-CH_3O-C_6H_4-\overset{+}{\mathop{C}},H_2 $

C) $ p-Cl-C_6H_4-\overset{+}{\mathop{C}},H_2 $

D) $ C_6H_5-\overset{+}{\mathop{C}},H_2 $

Show Answer

Answer:

Correct Answer: B

Solution:

Nitro-group is electron withdrawing therefore decreases stability.

Methoxy group is electron releasing.

Therefore increases stability by donating electron.

Chlorine is also electron withdrawing but its effect is less than $ -NO_2 $ group.

Hence, correct order of stability.



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