Some Basic Principles Of Organic Chemistry Question 170

Question: Number of structural isomers of $ C_4H_{10}O $ are [CPMT 1983, 84, 89, 91; MADT Bihar 1984; MNR 1984; MP PET 1997; Pb. PMT 1999; MH CET 2003]

Options:

A) 3

B) 6

C) 7

D) 10

Show Answer

Answer:

Correct Answer: C

Solution:

$ C_4H_{10}O $ have 7 isomers out of which 4 are alcohols and 3 are ethers.

1.$ \underset{n-butyl,alcohol}{\mathop{CH_3-CH_2-CH_2-CH_2-OH}}, $ ,

2.$ \underset{Sec-butyl,alcohol}{\mathop{CH_3-CH_2-\underset{OH}{\mathop{\underset{|,}{\mathop{CH}},}},-CH_3}}, $

3.$ \underset{Isobutyl,alcohol}{\mathop{CH_3-\underset{CH_3}{\mathop{\underset{|,}{\mathop{CH}},}},-CH_2-OH}}, $

4.$ \underset{Ter-buty-alcohol}{\mathop{CH_3-\overset{CH_3}{\mathop{\underset{\underset{OH}{\mathop{|}},}{\overset{|}{\mathop{C-,}}},}},CH_3}}, $

5.$ \underset{Diethyl,ether}{\mathop{CH_3-CH_2-O-CH_2-CH_3}}, $

6.$ \underset{Methyl,propyl,ether}{\mathop{CH_3-O-CH_2-CH_2-CH_3}}, $

7.$ \underset{Methyl,isopropyl,ether}{\mathop{CH_3-O-CH<_CH_3^{CH_3}}}, $



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