Some Basic Principles Of Organic Chemistry Question 112

Question: $ Cl-C-Cl $ angle in 1, 1, 2, 2 - tetrachloroethene and tetrachloromethane respectively are about [IIT-JEE 1988]

Options:

A) $ 120^{o} $ and $ {{109.5}^{o}} $

B) $ 90^{o} $ and $ {{109.5}^{o}} $

C) $ {{109.5}^{o}} $ and $ 90^{o} $

D) $ {{109.5}^{o}} $ and $ 120^{o} $

Show Answer

Answer:

Correct Answer: A

Solution:

$ 120{}^\circ $ and $ 109.5{}^\circ $

$ \underset{\text{Bond angle }=\text{ 12}{{0}^{o}}}{\mathop{\underset{sp^{2}\text{-hybridization}}{\mathop{Cl-\underset{Cl}{\mathop{\underset{|}{\mathop{C}},}},=\underset{Cl}{\mathop{\underset{|}{\mathop{C}},}},-Cl}},}}, $



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