Some Basic Principles Of Organic Chemistry Question 103

Question: A compound has an empirical formula $ C_2H_4O $ . An independent analysis gave a value of 132.16 for its molecular mass. What is the correct molecular formula [Kerala PMT 2004]

Options:

A) $ C_4H_4O_5 $

B) $ C_{10}H_{12} $

C) $ C_7O_3 $

D) $ C_6H_{12}O_3 $

E) $ C_4H_8O_5 $

Show Answer

Answer:

Correct Answer: D

Solution:

Empirical formula weight $ C_2H_4O $

$ =(12\times 2+4+16)=44 $ Molecular formula $ =\frac{mol\text{.wt}}{eq\text{.formula wt}\text{.}}\times $ Emp.

Formula $ =\frac{132.1}{44}\times \text{Emperical formula} $

$ =3\times C_2H_4O=C_6H_{12}O_3 $



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