Some Basic Concepts Of Chemistry Question 60

Question: A transition metal M forms a volatile chloride which has a vapour density of 94.8. If it contains 74.75% of chlorine the formula of the metal chloride will be

Options:

A) MCl3

B) MCl2

C) MCl4

D) MCl5

Show Answer

Answer:

Correct Answer: C

Solution:

[c] 74.75% of chlorine means 74.75g chlorine is present in 100g of metal chloride. Weight of metal = 100g74.75g =25.25g Equivalent weight =weightofmetalweightofchlorine×35.5 =25.2574.25×35.5=12 Valency of metal =2×V.D.Equivalentwt.ofmetal+35.5 =2×94.812+35.5=4

Formula of compound =MCl4



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