Some Basic Concepts Of Chemistry Question 280

Question: 3.92 g of ferrous ammonium sulphate crystals are dissolved in 100 ml of water, 20 ml of this solution requires 18 ml of $ KMnO _4 $ during titration for complete oxidation. The weight of $ KMnO _4 $ present in one litre of the solution is [Tamilnadu CET 2002]

Options:

A) 3.476 g

B) 12.38 g

C) 34.76 g

D) 1.238 g

Show Answer

Answer:

Correct Answer: A

Solution:

$ KMnO _4 $ = Mohr salt $ \frac{M _1V _1}{1}=\frac{M _2V _2}{5}=[ \frac{W}{M\times V}\times 1000 ]\times \frac{V _2}{5} $ $ [ \frac{W\times 1000}{58\times 1000} ]\times 18 $ $ =\frac{3.92\times 1000}{392\times 1000}\times \frac{20}{5} $ W=3.476gm/L.



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