Some Basic Concepts Of Chemistry Question 143

Question: The empirical formula of a compound composed of 38.4% potassium, 36.3% oxygen, 23.7% carbon and 1.66% hydrogen is determined to be

Options:

A)  KC2H5O4

B) K3C6H5O7

C) K2CHO3

D) K6C4H5O7

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Element %by mass Atomic mass Rel.no.of moles of element Simplest molar ratio K 38.4 39.10 38.439.10=0.982 0.9820.982=1 O 36.3 16.00 36.316.00=2.27 2.270.982=2.3 C 23.7 12.01 23.712.01=1.97 1.970.982=2.00 H 1.66 1 1.01 1.661.01=1.64 1.640.982=1.67 In this case fractions are in thirds so a factor of 3 will change Simple molar ratio Fraction nearest decimal value Nearest factor Whole no. mole ratio 1.00 mol K 1 mol K ×3 3 mol K 2.31 mol O 2 1/3 mol O ×3 7 mol O 2.01 mol C 2 mol C ×3 6 mol C 1.67 mol 4 1 2/3 mol H ×3 5 mol H Hence empirical formula is K3C6H5O7 which is formula of potassium citrate.



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