Some Basic Concepts Of Chemistry Question 137

Question: What weight of $ H _2C _2O _42H _2O(mol\text{.},wt\text{.},=126) $ should be dissolved to prepare 250 ml of cent normal to be used as a reducing agent?

Options:

A) 0.63 gm

B) 0.1575 gm

C) 0.126 gm

D) 0.875 gm

Show Answer

Answer:

Correct Answer: B

Solution:

[c] Per mole of given acid $ C _2O_4^{2-} $ present = 1 mole

$ \therefore $ $ C _2O_4^{2-}\to CO _2+2e $

$ \therefore $ x factor for $ H _2C _2O _4,2H _2O $ as a reducing agent = 2

$ \therefore $ equiv. wt. $ =\frac{250}{100}\times {10^{-3}}=63 $ 250 ml of seminormal solution $ =\frac{250}{100}\times {10^{-3}} $ equiv.

$ \therefore $ wt. of $ H _2C _2O _4,2H _2O $ required $ =\frac{250}{100}\times {10^{-3}}\times 63gm=0.1575gm $



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