Solutions Question 344

Question: The observed osmotic pressure for a 0.10 M solution of Fe(NH4)2(SO4)2,at,25C is 10.8 atm. The experimental (observed) value of van’t Hoff factor will be: (R=0.082Latmk1mol1)

Options:

A) 4.42

B) 4.00

C) 3.42

D) 5.42

Show Answer

Answer:

Correct Answer: A

Solution:

Given πob=10.8atm

πnor=CRT=0.10×0.0821×298=2.446 now experimental value of (i) =ObservedosmoticpressureNormalosmoticpressure

=10.82.446=4.42



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