Redox Reactions And Electrochemistry Ques 762

Question: $ 6\times {{10}^{-3}} $ mole $ K_2Cr_2O_7 $ reacts completely with $ 9\times {{10}^{-3}} $ mole of $ {{x}^{n+}} $ to give $ XO_3^{-} $ and $ C{{r}^{3+}} $ . Value of n will be

Options:

A) 1

B) 3

C) 2

D) 4

Show Answer

Answer:

Correct Answer: A

Solution:

[a] $ K_2Cr_2O_7+{{X}^{n+}}\xrightarrow[{}]{{}}{{X}^{5+}}O_3^{-}+C{{r}^{3+}} $ $ 6\times {{10}^{-3}}\times 6=(5-n)\times 9\times {{10}^{-3}} $ Implies $ n=1 $ In $ K_2Cr_2O_7 $ oxidation state of $ Cr=6 $ X have change in oxidation number $ =(5-n) $ .



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