Redox Reactions And Electrochemistry Ques 657

Question: The oxidation state of nitrogen is correctly given for

Options:

A) Compound Oxidation state $ [ Co{{( NH_3 )}_5}Cl ]Cl_2 $ 0

B) Compound Oxidation state $ NH_2OH $ -2

C) Compound Oxidation state $ {{(N_2H_5)}_2}SO_4 $ +2

D) Compound Oxidation state $ Mg_3N_2 $ -3

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Answer:

Correct Answer: D

Solution:

[d] $ {{[ \overset{+3}{\mathop{Co}},{{( N{{\overset{0}{\mathop{H}},}_3} )}_5}\overset{-1}{\mathop{Cl}}, ]}^{+2}}\overset{-1\times 2}{\mathop{Cl_2}}, $ $ +3+5x+15-1=+2 $ $ 5x+17=+2 $ $ 5x=-15 $ $ x=-3; $ Oxidation State of $ N=-3 $

[b] $ NH_2OH:x+3-2=0\Rightarrow x=-1 $ Oxidation state of $ N=-1 $

[c] $ {{(N_2H_5)}^{+1}}SO_4^{2-}: $ $ N_2H_5^{+}:2x+5=+1\Rightarrow x=-2 $ Oxidation number of $ N=-2 $

[d] $ Mg_3N_2:2\times 3+2x=0 $ $ 2x=-6 $ $ x=-3 $ Oxidation state of $ N=-3 $



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