Redox Reactions And Electrochemistry Ques 647

Question: For a given reaction: $ M(x+n)+n{e^{-}}\xrightarrow{{}}{M^{x+}},{E^{-}}_{red} $ is known along with $ {M^{(x+n)}} $ and $ {M^{x+}} $ ion concentrations. Then

Options:

A) n can be evaluated

B) x can be evaluated

C) $ ( x+n ) $ can be evaluated

D) $ n,x,( x+n ) $ can be evaluated

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Answer:

Correct Answer: A

Solution:

[a] $ E_{red}=E_red^{{}^\circ }+\frac{0.059}{n}\log \frac{[{M^{(x+n)}}]}{[{M^{x+}}]} $ here apart from n, all are known so we can calculate value of n by this equation.



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