Equilibrium Question 908

Question: Solubility of PbCl2 in 0.5 M NaCl is S1 and that in 0.5 M Pb(NO3)2 is S2 then which of 5 the following is correct:

Options:

A) S1S2=1

B) S1S2>0

C) S1S2<0

D) S1S2>1

Show Answer

Answer:

Correct Answer: C

Solution:

S1=Ksp0.52,,S2=Ksp0.5

S1S2=Ksp0.52×0.5Ksp=Ksp0.5×0.5=Ksp0.707×0.5

But Ksp«<1

S1S2<1

S1<S2

S1S2<0



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