Equilibrium Question 904

Question: The solubility product of $ Mg{{(OH)}_2} $ is $ {10^{-14}} $ . The solubility of $ Mg{{(OH)}_2} $ in a buffer solution of $ pH=8 $ is

Options:

A) $ {10^{-8}} $

B) $ {10^{-6}} $

C) $ {10^{-2}} $

D) $ {10^{-4}} $

Show Answer

Answer:

Correct Answer: C

Solution:

$ Mg{{(OH)}_2},M{g^{2+}},+2O{H^{-}} $

$ K _{sp}=[M{g^{2+}}]{{[O{H^{-}}]}^{2}} $

$ 1\times {10^{-14}}=[M{g^{2+}}],{{[{10^{-6}}]}^{2}} $

$ \because $ $ pH=8 $

$ \therefore $ $[{H^{+}}]={10^{-8}},mol,{L^{-1}} $ . and $ [O{H^{-}}]={10^{-6}}mol{L^{-1}}] $

$ [M{g^{2+}}]=\frac{{10^{-14}}}{{10^{-12}}}={10^{-2}}mol,{L^{-1}} $

Solubility $ [M{g^{2+}}]={10^{-2}},mol{L^{-1}} $



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