Equilibrium Question 836

Question: The degree of hydrolysis in hydrolytic equilibrium A +H2OHA+OH at salt concentration of 0.001 M is : (Ka=1×105)

Options:

A) 1×103

B) 1×104

C) 5×104

D) 1×106

Show Answer

Answer:

Correct Answer: A

Solution:

(Initial),(Ateq.),A 0.001M (0.001R), +H2OHA0,(0.001,×,h),+HA0,(0.001,×,h),

Kh=(0.001×h)(0.001×h)(0.001h) or, Kh=0.001×h2(as,0.001h0.001)

109=0.001×h2

(Kh=KwKa=1014105=109)

h2=106;

h=103



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