Equilibrium Question 796

Question: Assuming that the degree of hydrolysis is small, the pH of 0.1 M solution of sodium acetate $ (K_{a}=1.0\times {10^{-5}}) $ will be:

Options:

A) 5.0

B) 6.0

C) 8.0

D) 9.0

Show Answer

Answer:

Correct Answer: D

Solution:

Sodium acetate is a salt of strong base and weak acid.
$ \therefore pH=7+\frac{1}{2}pK_{a}=\frac{1}{2}logc $ where $ pK_{a}=-\log K_{a}=-log{10^{-5}}=5 $

$ logc=log{10^{-1}}=-1 $

$ pH=7+\frac{5}{2}-\frac{1}{2}=9.0 $



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