D-And F-Block Elements Ques 420

Question: Four successive members of the first row transition elements are listed below with their atomic numbers. Which one of them is expected to have the highest third ionization enthalpy

[CBSE PMT 2005]

Options:

A) Vanadium (Z = 23)

B) Chromium (Z = 24)

C) Iron (Z = 26)

D) Manganese (Z = 25)

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Answer:

Correct Answer: D

Solution:

$ _{25}Mn=3d^{5}4s^{2} $ After losing two electron electronic configuration will be like this $ _{25}M{{n}^{++}}3d $ and this is most stable configuration due to half filled orbitals hence third ionization enthalpy will be highest in this case.



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