Co-Ordination Compounds Question 56

Question: In any ferric salt, on adding potassium ferrocyanide, a prussian blue colour is obtained, which is

[BIT 1992; BHU 2002]

Options:

A) $ K_3Fe{{(CN)}_6} $

B) $ KFe[ Fe{{( CN )}_6} ] $

C) $ FeSO_4.Fe{{(CN)}_6} $

D) $ Fe_4{{[ Fe{{(CN)}_6} ]}_3} $

Show Answer

Answer:

Correct Answer: D

Solution:

$ \underset{pot\text{.ferrocyanide}}{\mathop{3,K_4[Fe{{(CN)}_6}]+4FeCl_3}},\to \underset{\text{(Prussion blue)}}{\mathop{\underset{\text{(Ferri ferrocynide)}}{\mathop{Fe_4{{[Fe{{(CN)}_6}]}_3}+,12KCl}},}}, $



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