Co-Ordination Compounds Question 291

Question: Complexes $ [ Co{{( NH_3 )}_5}SO_4 ]Br $ and $ [ Co{{( NH_3 )}_5}Br ]SO_4 $ can be distinguished by

Options:

A) conductance measurement

B) using $ BaCl_2 $

C) using $ AgNO_3 $

D) Both [b] and [c]

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Answer:

Correct Answer: D

Solution:

$ [ Co{{( NH_3 )}_5}Br ]SO_4 $ gives white precipitate of $ BaSO_4 $ with $ BaCl_2(aq) $ whereas $ [ Co{{( NH_3 )}_5}SO_4 ]Br $ gives yellow precipitate $ ( AgBr ) $ with $ AgNO_3(aq) $ .



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