Co-Ordination Compounds Question 267

Question: In the silver plating of copper, $ K[Ag{{( CN )}_2}] $ is used instead of $ AgNO_3 $ . The reason is

Options:

A) a thin layer of Ag is formed on Cu

B) more voltage is required

C) $ A{g^{+}} $ ions are completely removed from solution

D) less availability of $ A{g^{+}} $ ions, as Cu cannot displace Ag from $ {{[Ag{{(CN)}_2}]}^{-}} $ ion.

Show Answer

Answer:

Correct Answer: D

Solution:

In silver plating $ K[Ag{{(CN)}_2}] $ is used which provides constant and required supply of $ A{g^{+}} $ ions as $ Ag{{(CN)}_2}^{-} $ is very stable.

But if $ AgNO_3 $ is used concentration of $ [A{g^{+}}] $ in solution will be very large.

In that case Ag will be deposited at faster rate without any uniformity.



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