Co-Ordination Compounds Question 241

Question: For octahedral complex, which of the following $ d^{n} $ configurations of metal cation cannot exist in high spin and low spin forms?

Options:

A) $ d^{3} $ and $ d^{8} $

B) $ d^{3} $ and $ d^{5} $

C) $ d^{3} $ and $ d^{6} $

D) $ d^{4} $ and $ d^{8} $

Show Answer

Answer:

Correct Answer: A

Solution:

In $ d^{3} $ and $ d^{8} $ octahedral complexes number of unpaired $ {e^{-}} $ s at central metal atom/ion never changes, therefore for such octahedral complexes terms high spin and low spin not used.



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