Co-Ordination Compounds Question 238
Question: In which of the following complex hybridization of central metal is not same as that of donor atom of ligand
Options:
A) $ [ Ni{{( PF_3 )}_4} ] $
B) $ [ Fe{{( dmg )}_2} ] $
C) $ {{[Zn,{{(en)}_2}]}^{2+}} $
D) $ {{[ Ni{{( PMe_3 )}_4} ]}^{2+}} $
Show Answer
Answer:
Correct Answer: B
Solution:
[a] $ [ Ni{{(PF_3)}_4} ] $
$ Ni:sp^{3} $ Hybridization $ P:sp^{3} $ Hybridization [b] $ [ Fe{{(dmg)}_2} ] $
$ Fe:dsp^{2} $ Hybridization N-atom of dmg: $ sp^{3} $ Hybridization [c] $ {{[Zn,{{(en)}_2}]}^{2+}} $
$ Zn:sp^{3} $ Hybridization N-atom of en: $ sp^{3} $ Hybridization [d] $ {{[Ni{{(PMe_3)}_4}]}^{2+}} $
$ Ni:sp^{3} $ Hybridization $ P:sp^{3} $ Hybridization
