Co-Ordination Compounds Question 228

Question: $ M{n^{2+}} $ forms a complex with $ B{r^{-}} $ ion. The magnetic moment of the complex is 5.92 B.M. What would be the probable formula and geometry of the complex?

Options:

A) $ {{[MnBr_6]}^{4-}} $ , octahedral

B) $ {{[MnBr_4]}^{2-}} $ , square planar

C) $ {{[MnBr_4]}^{2-}} $ , tetrahedral

D) $ {{[MnBr_5]}^{3-}} $ , trigonal bipyramidal

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Answer:

Correct Answer: C

Solution:

Magnetic moment, $ \sqrt{n(n+2)}=5.92,B.M.$

$ \Rightarrow n $ (unpaired electrons) = 5 $ sp^{3} $ hybridization (tetrahedral)



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