Co-Ordination Compounds Question 125

Question: The total number of possible isomers for the complex compound $ [ Cu^{II}{{(NH_3)}_4} ],[ Pt^{II}Cl_4 ] $ are

[CBSE PMT 1998; DPMT 2004; J & K CET 2005]

Options:

A) 3

B) 4

C) 5

D) 6

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Answer:

Correct Answer: D

Solution:

$ [Cu,{{(NH_3)}_4}],.,[Pt,Cl_4] $ 2.

$ [Cu,{{(NH_3)}_3}Cl],.,[Pt,Cl_3(NH_3)] $ 3.

$ [Cu,{{(NH_3)}_2}Cl_2].[Pt,Cl_2{{(NH_3)}_2}],cis $ 4.

$ [Cu,{{(NH_3)}_2}Cl_2].[Pt,Cl_2{{(NH_3)}_2}],Trans $ 5.

$ [Cu,(NH_3)Cl_3].[Pt(Cl){{(NH_3)}_3}] $ 6.

$ [,Pt,{{(NH_3)}_4}Cl,],.,[Cu,Cl_4] $



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