Co-Ordination Compounds Question 115

Question: Among the following ions which one has the highest paramagnetism

[IIT 1993; UPSEAT 2002]

Options:

A) $ {{[ Cr{{(H_2O)}_6} ]}^{3+}} $

B) $ {{[ Fe{{(H_2O)}_6} ]}^{2+}} $

C) $ {{[ Cu{{( H_2O )}_6} ]}^{2+}} $

D) $ {{[ Zn{{( H_2O )}_6} ]}^{2+}} $

Show Answer

Answer:

Correct Answer: B

Solution:

$ {{[Fe{{(H_2O)}_6}]}^{2+}} $ has four unpaired electrons, $ {{[Cr{{(H_2O)}_6}]}^{3+}}, $

$ {{[Cu{{(H_2O)}_6}]}^{2+}} $ and $ {{[Zn{{(H_2O)}_6}]}^{2+}} $ have 3, 1, 0 unpaired electrons respectively.



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