Co-Ordination Compounds Question 111

Question: $ [ Co{{( NH_3 )}_4}Cl_2 ]NO_2 $ and $ [ Co{{( NH_3 )}_4}Cl.NO_2 ]Cl $ are …….. isomers

[MP PMT 1993; MP PET 1995, 2001]

Options:

A) Geometrical

B) Optical

C) Linkage

D) Ionization

Show Answer

Answer:

Correct Answer: D

Solution:

Both produce different ions in solution state- $ [Co{{(NH_3)}_4}Cl_2]NO_2 $ ⇌ $ {{[Co{{(NH_3)}_4}Cl_2]}^{+}}NO_2^{-} $

$ [Co{{(NH_3)}_4}Cl.,NO_2]Cl $ ⇌ $ {{[Co{{(NH_3)}_4}Cl,.,NO_2]}^{+}}+C{l^{-}} $



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