Chemical Thermodynamics Question 469

Question: The tendency of a reaction to take place spontaneously is greatest when the reaction is

Options:

A) Exothermic and randomness increases

B) Endothermic & randomness increases

C) Exothermic and randomness decreases

D) Endothermic & randomness decreases

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Answer:

Correct Answer: A

Solution:

  • For exothermic reaction $ \Delta H=-ve $ and if randomness increases it means $ \Delta S $ becomes positive. Thus according to $ \Delta G=\Delta H-T\Delta S;,\Delta G $ becomes $ -ve, $ so the reaction is spontaneous.


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