Chemical Thermodynamics Question 238

Question: The enthalpy of combustion of benzene from the following data will be (i) $ 6C(s)+3H_2(g)\to C_6H_6(l);,\Delta H=+45.9,kJ $ (ii) $ H_2(g)+\frac{1}{2}O_2(g)\to H_2O(l);,\Delta H=-285.9,kJ $ (iii) $ C(s)+O_2(g)\to CO_2(g);,\Delta H=-393.5,kJ $

Options:

A) + 3172.8 kJ

B) - 1549.2 kJ

C) - 3172.8 kJ

D) - 3264.6 kJ

Show Answer

Answer:

Correct Answer: D

Solution:

Multiplying eq. (ii) by (iii) and eq. (iii) by (vi), and then add $ 6,C+3H_2+\frac{15}{2}O_2\to $

$ 6,CO_2+6H_2O;\Delta H=3218.7 $ Subtract eq. (i) from the above equation and find the required result.



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