Chemical Bonding And Molecular Structure Question 485

Question: Which of following statement is true-

Options:

A) Absolutely pure water does not contain any ions

B) London forces is directly proportional to more number of loosely held electron

C) Allene is polar due to its non-planar structure

D) CH3OCH3 is less volatile than C2H5OH due to higher molecular weight.

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Answer:

Correct Answer: B

Solution:

(1) H2OH++OH Kw=1014 at 25o Even in conductivity water (H2O) is found to be dissociated into H+ and OH . (2) More the number of loosely held electron, greater will be their tendency for being polarized deformed i.e., the magnitude of formal charge increases, hence London forces increases. (3) H2C=C=CH2 (Non planar) μD=0 (4) In CH3COCH3 there is no H-bonding hence more volatile, while in C2H5OH intermolecular H-bonding is present hence less volatile, due to association.



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