Chemical Bonding And Molecular Structure Question 464

Question: Which one of the following molecules is paramagnetic-

Options:

A) $ N_2 $

B) NO

C) CO

D) $ O_3 $

Show Answer

Answer:

Correct Answer: B

Solution:

  • The molecular orbital configuration of the molecules given is Total no. of electrons in $ NO=7( N )+8( O ) $

$ =15 $
Hence E.C. of NO $ =KK\sigma {{(2s)}^{2}}\sigma *{{(2s)}^{2}}\sigma {{(2p_{z})}^{2}} $

$ \pi {{(2p_{x})}^{2}}=\pi {{(2p_{y})}^{2}}\pi *{{(2p_{x})}^{1}}=\pi {{(2p_{y})}^{0}} $ Due to presence of one unpaired electron NO is paramagnetic. Except NO all are diamagnetic due to absence of unpaired electrons.



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