Chemical Bonding And Molecular Structure Question 464

Question: Which one of the following molecules is paramagnetic-

Options:

A) N2

B) NO

C) CO

D) O3

Show Answer

Answer:

Correct Answer: B

Solution:

  • The molecular orbital configuration of the molecules given is Total no. of electrons in NO=7(N)+8(O)

=15
Hence E.C. of NO =KKσ(2s)2σ(2s)2σ(2pz)2

π(2px)2=π(2py)2π(2px)1=π(2py)0 Due to presence of one unpaired electron NO is paramagnetic. Except NO all are diamagnetic due to absence of unpaired electrons.



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