chemistry-class-12-unit-11-chapter-03-alcohols-l-3-6-fbwnwha3uvu

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Reactions of alcohols</B></primary></p>
<hr>
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<div style='float: left; width:100%;font-size:22px;text-align:left'>



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<footer style="font-size:18px;"> <span style="color:blue">Reactions of alcohols</span> $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Compare acidity constants of alcohols</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<table>
<thead>
<tr>
<th></th>
<th>pka</th>
</tr>
</thead>
<tbody>
<tr>
<td>$CH_3OH$</td>
<td>15.5</td>
</tr>
<tr>
<td>$H_2O$</td>
<td>15.74</td>
</tr>
<tr>
<td>$CH_3CH_2OH$</td>
<td>15.90</td>
</tr>
<tr>
<td>$(CH_3)_3-C-OH$</td>
<td>18.0</td>
</tr>
<tr>
<td>$CH \equiv CH$</td>
<td>25.0</td>
</tr>
<tr>
<td>$H_2$</td>
<td>35.0</td>
</tr>
<tr>
<td>$NH_3$</td>
<td>38.0</td>
</tr>
<tr>
<td>$CH_3-CH_3$</td>
<td>50.0</td>
</tr>
</tbody>
</table>
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<p><img alt="image" src="/subject-images/iitpal/image/chemistry-class-12-unit-11-chapter-03-alcohols-l-3_6-fbwnwha3uvu-02.jpg"></p>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ <span style="color:blue">Compare acidity constants of alcohols</span> $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Compare acidity constants of alcohols</B></primary></p>
<hr>
<main>
<div style='float: left; width:60%;font-size:22px;text-align:left'>

<ul>
<li>
<p><strong>Relative acidity</strong></p>
</li>
<li>
<p>$H_2O>ROH>RC \equiv CH>H_2>NH_3>RH$</p>
</li>
<li>
<p>all alcohols except methanol are weaker acids than water</p>
</li>
</ul>
</div>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ <span style="color:blue">Compare acidity constants of alcohols</span> $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Basicity</B></primary></p>
<hr>
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<div style='float: left; width:60%;font-size:22px;text-align:left'>
<ul>
<li>
<p><strong>Basicity order</strong></p>
</li>
<li>
<p>$CH_3O^-<OH^-<CH_3CH_2O^-<(CH_3)_3CO^-<CH \equiv C^-H<H^-<NH_2^-<CH_3CH_2^-$</p>
</li>
<li>
<p>Electronic effect R</p>
</li>
<li>
<p>Extent of solvation of conjugate base</p>
</li>
</ul>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ <span style="color:blue">Basicity</span> $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Reactions replacing</B></primary></p>
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<div style='float: left; width:100%;font-size:22px;text-align:left'>
<p>(A) Reactions replacing H atom $1^o>2^o>3^o$</p>
<ul>
<li>
<p><strong>(1) With active metals</strong> $(Na, K, Al, Mg)$</p>
</li>
<li>
<p>$2ROH+2Na \rightarrow 2RONa+H_2 \uparrow$</p>
</li>
<li>
<p>$ROH+M \rightarrow RO^-M^+ \frac{1}{2}H_2 \uparrow$</p>
</li>
<li>
<p><strong>(2) With grignard’s reagents</strong> react with active hydrogen</p>
</li>
<li>
<p>$ROH (stronger \hspace{1mm} acids) +R’MgX \rightarrow R’H+ROMgX$</p>
</li>
</ul>
</div>
<div style='float: right; width:0%;'>
<p><img alt="image" src="/subject-images/iitpal/image/chemistry-class-12-unit-11-chapter-03-alcohols-l-3_6-fbwnwha3uvu-04.jpg"></p>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ <span style="color:blue">Reactions replacing</span> $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Organic acids</B></primary></p>
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<p><strong>(3) with organic acids in presence of conc</strong> $H_2SO_4$- esters</p>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ <span style="color:blue">Organic acids</span> $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Reaction</B></primary></p>
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<p><strong>(4) With acid chloride or anhydride</strong> $(RCOCl or (RCO)_2O))$ $\rightarrow $ ester</p>

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<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ <span style="color:blue">Reaction</span> $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Phosphoric acid</B></primary></p>
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<p><strong>(5) With phosphoric acid</strong></p>

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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ <span style="color:blue">Phosphoric acid</span> $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Good leaving group</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<ul>
<li>
<p>$CF_3SO_2Cl \rightarrow $ triflates</p>
</li>
<li>
<p>$ArSO_2Cl PTSCl \rightarrow$ tosylates</p>
</li>
<li>
<p>$R-\ddot O_{..}H+ClSO_2R’ \xrightarrow [{-psyr HCl}]{Pry} ROSO_2R’+HCl$</p>
</li>
</ul>
</div>
<div style='float: right; width:0%;'>

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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ <span style="color:blue">Good leaving group</span> $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Good leaving group</B></primary></p>
<hr>
<main>
<div style='float: left; width:50%;font-size:22px;text-align:left'>
<ul>
<li><strong>Reaction</strong></li>
</ul>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ <span style="color:blue">Good leaving group</span> $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Halogen acids</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<ul>
<li>
<p><strong>Reactions replacing OH group</strong></p>
</li>
<li>
<p><strong>With halogen acids</strong> HI-(temperature below HI)HBr-(conc HBr or KBr/NaBr + $H_2SO_4 \rightarrow$ nylux) HCl-(conc HCl+anhydrous$ZnCl_2$ lewis acids $\rightarrow$ heat)</p>
</li>
<li>
<p>Substitution reaction $\rightarrow$ acid catalyzed</p>
</li>
<li>
<p>$R-OH + HX \rightarrow RX + H_2O$</p>
</li>
<li>
<p>prommates OH, makes it a good leaving group</p>
</li>
</ul>
</div>
<div style='float: right; width:0%;'>
<p><img alt="image" src="/subject-images/iitpal/image/chemistry-class-12-unit-11-chapter-03-alcohols-l-3_6-fbwnwha3uvu-10.jpg"></p>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ <span style="color:blue">Halogen acids</span> $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Lucas reagent</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<ul>
<li>
<p><strong>Reaction</strong></p>
</li>
<li>
<p>$3^o>2^o>1^o$</p>
</li>
<li>
<p>$1^o$, $CH_3CH_2CH_2CH_2CH_2OH(n-pentyl \hspace{1mm} alcohol) \xrightarrow [{anhydrous ZnCl_2, \Delta}]{HCl} CH_3CH_2CH_2CH_2CH_2Cl$(n-pentyl chlorids)</p>
</li>
<li>
<p>$2^o$, $>-OH( isopropylalcohol) \xrightarrow [{NaBr,H_2SO_4,reflux}]{conc HBr or} >-Br$</p>
</li>
<li>
<p>$3^o$, $t-butylalcohol \xrightarrow [{RT}]{conc HCl}$ t-butyl chloride</p>
</li>
</ul>
</div>
<div style='float: right; width:0%;'>
<p><img alt="image" src="/subject-images/iitpal/image/chemistry-class-12-unit-11-chapter-03-alcohols-l-3_6-fbwnwha3uvu-12.jpg"></p>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ <span style="color:blue">Lucas reagent</span> $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Phosphorus halides</B></primary></p>
<hr>
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<p><strong>(2) With phosphorus halides</strong> $(PCl_5,PBr_3, P/I_3, P/Br) \rightarrow $ allyl halides</p>

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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ <span style="color:blue">Phosphorus halides</span> $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Phosphorus halides</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<ul>
<li><strong>Reaction</strong></li>
</ul>

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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ <span style="color:blue">Phosphorus halides</span> $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Phosphorus halides</B></primary></p>
<hr>
<main>
<div style='float: left; width:60%;font-size:22px;text-align:left'>
<ul>
<li>
<p><strong>Reaction</strong></p>
</li>
<li>
<p>$1^o$ or $2^o$ alcohals</p>
</li>
<li>
<p>no carbocation formation</p>
</li>
<li>
<p>no rearrangement especially at/ under $0^oC$</p>
</li>
<li>
<p>$PBr_3$ preferred reagent food alkyl bromide fomation</p>
</li>
</ul>


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<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ <span style="color:blue">Phosphorus halides</span> $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Thionyl chloride</B></primary></p>
<hr>
<main>
<div style='float: left; width:60%;font-size:22px;text-align:left'>
<p><strong>(3) With thionyl chloride</strong> $\rightarrow$ allyl chloride</p>
<ul>
<li>$ROH+SOCl_2 \xrightarrow {pyr} RCl+ SO_2(g)\uparrow+HCl(gases)\uparrow$</li>
</ul>
</div>
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<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ <span style="color:blue">Thionyl chloride</span> $\rightarrow$ Oxidation $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Oxidation</B></primary></p>
<hr>
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<div style='float: left; width:100%;font-size:22px;text-align:left'>
<p><strong>(C) Reactions involving both R and OH groups</strong></p>
<ul>
<li>
<p>Oxidation, dehydro generation, dehydration</p>
</li>
<li>
<p><strong>OXIDATION of alcohols</strong></p>
</li>
<li>
<p>a number of oxidizing agents</p>
</li>
<li>
<p>($1^o \rightarrow$ $2^o \rightarrow$ $3^o) \rightarrow$</p>
</li>
</ul>
</div>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ <span style="color:blue">Oxidation</span> $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Oxidation</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<ul>
<li>
<p><strong>OXIDATION of alcohols</strong></p>
</li>
<li>
<p>Mn (VII) and Ge(VI)</p>
</li>
<li>
<p>Mn(VII) $KMnO_4 \rightarrow$ acidified $KMnO_4$, alkaline $KMnO_4$</p>
</li>
<li>
<p>$1^o \rightarrow$ acid</p>
</li>
<li>
<p>$RCH_2OH \xrightarrow {KMnO_4} R-COOM$</p>
</li>
</ul>
</div>
<div style='float: right; width:0%;'>
<p><img alt="image" src="/subject-images/iitpal/image/chemistry-class-12-unit-11-chapter-03-alcohols-l-3_6-fbwnwha3uvu-17.jpg"></p>
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<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ <span style="color:blue">Oxidation</span> $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Oxidation</B></primary></p>
<hr>
<main>
<div style='float: left; width:60%;font-size:22px;text-align:left'>
<ul>
<li>
<p><strong>Reaction</strong></p>
</li>
<li>
<p>No loss of C atoms</p>
</li>
<li>
<p>$R-CH_2OH \xrightarrow [{KMnO_4,OH^-,H_2O, \Delta}]{basic aq.} R-COO^-K^+ \xrightarrow {H^+} RCOOH+MnO_2\downarrow$brown ppt</p>
</li>
<li>
<p>Cr(VI) $\rightarrow CrO_3/dil H_2SO_4$ in aq acetone chromic acid $H_2CrO_4$</p>
</li>
</ul>
</div>
<div style='float: right; width:40%;'>
<img src="https://imagedelivery.net/YfdZ0yYuJi8R0IouXWrMsA/109289f9-e976-4251-0cb6-5dc64b4b8900/public" width="100%" >
</div>
</main>
<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ <span style="color:blue">Oxidation</span> $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Oxidation</B></primary></p>
<hr>
<main>
<div style='float: left; width:60%;font-size:22px;text-align:left'>
<ul>
<li>
<p><strong>Reaction</strong></p>
</li>
<li>
<p>Jones reagent</p>
</li>
<li>
<p>$H_2CrO_4$ or $Na_2Cr_2O_7$ in $H_2SO_4$ water</p>
</li>
<li>
<p>$RCH_2OH(1^o), Cr_2O_7^{2-}$(orange red)</p>
</li>
<li>
<p>$R-CH=O+Cr^{2+} \xrightarrow {Cr_2O_7^{2-}} RCOOH$</p>
</li>
</ul>
</div>
<div style='float: right; width:40%;'>
<img src="https://imagedelivery.net/YfdZ0yYuJi8R0IouXWrMsA/109289f9-e976-4251-0cb6-5dc64b4b8900/public" width="100%" >

</div>
</main>
<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ <span style="color:blue">Oxidation</span> $\rightarrow$ Mechanism of oxidation </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Mechanism of oxidation</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<ul>
<li>Mechanism of oxidation $1^o ROH \rightarrow$ old acid</li>
</ul>
</div>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<img src="https://imagedelivery.net/YfdZ0yYuJi8R0IouXWrMsA/bba57a6f-2171-4b91-0324-ab7e6f4b9f00/public" width="40%" >

</div>
</main>
<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ <span style="color:blue">Mechanism of oxidation</span> </footer>

<p><Success style="float:center;text-align:center;font-size:28px;"> <B>Alcohols Lecture-3</B></Success></p>
<p><primary style="float:center;text-align:center;font-size:24px;"> <B>Mechanism of oxidation</B></primary></p>
<hr>
<main>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<ul>
<li><strong>Reaction</strong></li>
</ul>
</div>
<div style='float: left; width:100%;font-size:22px;text-align:left'>
<img src="https://imagedelivery.net/YfdZ0yYuJi8R0IouXWrMsA/54a913c5-0d0f-4007-c8fb-26deaf30c100/public" width="30%" >

</div>
</main>
<hr>
<footer style="font-size:18px;"> Reactions of alcohols $\rightarrow$ Compare acidity constants of alcohols $\rightarrow$ Basicity $\rightarrow$ Reactions replacing $\rightarrow$ Organic acids $\rightarrow$ Reaction $\rightarrow$ Phosphoric acid $\rightarrow$ Good leaving group $\rightarrow$ Halogen acids $\rightarrow$ Lucas reagent $\rightarrow$ Phosphorus halides $\rightarrow$ Thionyl chloride $\rightarrow$ Oxidation $\rightarrow$ <span style="color:blue">Mechanism of oxidation</span> </footer>