Surface chemistry Lecture-5
Surface chemistry
logA Vs $E^{cat}_a$
$k^{cat}$=$A^{cat}$ $e^-{\frac{E^{cat}_a}{RT}}$
$k^{uncat}=A^{uncat}$ $e^-{\frac{E^{uncat}_a}{RT}}$
Zeolite catalysts - $SiO^{4-}_4$, $AlO^{5-}_4$
Lewis and bronsted
Enzyme catalysis
Smoke
Homogenized milk
Shampoo COLLOIDS/EMULSIONS
Colloids
What is a colloid ?
Thomas Graham 1851 - diffusion of gases
Colloidal chemistry is Wolfgang Ostwald “world of neglected dimensions”
Chemistry of grains , Drops , bubbles , filaments and films
Chemistry of everyday life solution
It has two components
1.) Dispersed phase
continuous / dispersion phase
Emulsifying agent
2.) Dispersion medium
Types of colloids
Many processes involve colloidal phenomena
Adhesion
Detergency
Road surfacing
Electrophoretic deposition
Sewage disposal
Emulsion polymerisation
Soil conditioning
Food processing
Sugar refining
Lubrication wetting
Oil - well drilling
Common colloids
Aerosols
Agrochemicals
Cement
Cosmetics
Dyestuffs
Emulsions
Fabrics
Foams
Foodstuffs
Ink
Paint
Paper
Pharmaceuticals
Plastics
Rubber
Soil
Differences between colloids and classical chemistry
Properties of colloids
(1) Optical
(2) Kinetic
(3) Stability
(1) Optical - dust particles scattering light tyndall effect
Tyndall effect - colloidal optical property
Zsigmondy 1909 - ultramicroscopy
Diffusion
Brownian
Dialysis
Electrokinetic
Electrophoresis
Electro - osmosis
Streaming potential
Dialysis - Thomes Gochan
Kidney dialysis to semi permeable membrane
[Urea/creatines $\rightarrow$ urine]
Preparation of colloids
Condansation (Bottom - up)
Dispersion(Top - down)
(1) $FeCl_3$ $H_2O$ $100^oC$ $Fe(OH)_3$
(2) $AuCl_4 + 4 Au ~ $
$Au^0$
$AgI \left[Ag^+\right]=\left[I\right]=10^{-8}$
$KI+AgNO_3 \rightarrow AgI$
$AgNO_3$
Thank you