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Organic Chemistry Basic Principles And Techniques L-05
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Basic priciple and techniques
![image](https://temp-public-img-folder.s3.ap-south-1.amazonaws.com/sathee.prutor.images/subject-images/iitpal/image/chemistry-class-11-unit-12-chapter-05-organic-chemistry-basic-principles-and-techniques-l-05_7-hq9dlpkqmou-1.png)
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of reagents
- Free radicals-add electron species - Electrophiles - specious that are electrophiles deficient/attracted to electrons - Nucleophic - Species that are electrophiles rich/attraacted to electron deficient
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of reagents
* Free radicals - Addition to double and triple bonds-if the free radical formed is more stable than the free radical reacting then reaction is favouable - H-abstraction reaction - formation of trietyl radical
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of reagents
* Electrophiles - $H^+$ is an electrophile, it can add to electron rich double bond by protonation reaction * Example
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of reagents
* Generation of electrophilic reagent
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of reagents
* Nucleophile - Strong nucleophile are $CN^-$ $O^-H$ $CH_3O^-$ $N^-_3$ $PhS^-$ $Cl^-,Br^-$ - Mild nucleophile - $R_3N:$ * Substitution reaction using a nucleophile * Addition reaction using a nucleophile
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Arrow pushing mechanism - Arrow starts from electron rich center - Arrow head pointing at an electron deficient center * Substitution reaction is of two types | Electrophilic | Nucleophilic | | -------- | -------- | | Aliphatic | Aliphatic | | Aromatic | Aromatic |
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Organic Chemistry Basic Principles And Techniques L-05
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Substitution reaction
* Aliphatic nucleophilic substitution reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Substitution reaction
* Aliphatic electrophilic substitution reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Substitution Reaction
* Aromatic electrophilic substitution reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Substitution Reaction
* Aromatic electrophilic substitution reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Substitution reaction
* Aromatic nucleophilic substitution reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Addition reaction - Electrophilic - Nucleophilic
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Neutral (cyclo) * Electrophilic addition reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Addition nucleophilic reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Elimination reaction - $\beta$ elimination reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Elimination reaction - $\alpha$ elimination reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Rearrangemet reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Classification of organic reaction
* Rearrangemet reaction
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Organic Chemistry Basic Principles And Techniques L-05
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Thank you
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