Eel becomes negative as the particles approach each other
If A+ is approaching B− , there is attraction between them and the energy is decreased
Chemical Bonding Molecular Structure L-1
Chemical bonds
A+B−forms ionic bond
For example -
HA+HB→H−H
Chemical Bonding Molecular Structure L-1
Covalent bond
Distance between two hydrogen atom is 74pm
HA74pmHB
74pm is called bond length
Energy is −432kJ/mol
432kJ/mol of energy is to be given to cleave the H2
432kJ/ mol is the bond energy of the bond in H−H molecule
HA74pmHB this bond is called covalent bond
Chemical Bonding Molecular Structure L-1
Types of bond
Covalent bond - Sharing of pair of electrons between two atoms
Ionic bond - Type of linkage formed from the electrostatic attraction between oppositely charged ions in a chemical compound such a bond forms when the valence (outermost) electrons of one atom are transferred permanently to another atom
Metallic bond - Shared electrons are delocalized
Chemical Bonding Molecular Structure L-1
Lewis structures
G⋅N. Lewis proposed octet rule means eight
For second row elements, n = 2 , s(2e−) & p(6e−) orbitals - 8e−
Closed shell configuration for nobel gases
Single bond (means 2e−) shared between two atoms
Double bond (means 4e−) shared between two atoms
Chemical Bonding Molecular Structure L-1
Lewis symbol
Boron has 3 valence electron which can be shown like this
.B.˙
Carbon has 4 valence electrons which can be shown like this
:C:
Chemical Bonding Molecular Structure L-1
Drawing Lewis structures
Step 1 - Determine the number of valence electrons
H2O
2 × H+ 0 = 0
2 × 1 + 6 = 8e−
Total electrons = 8
Step 2 - Determine the central atom
Central atom is the one has the greatest bonding capacity
.B.˙:C:
Chemical Bonding Molecular Structure L-1
Drawing lewis structures
Step 3 - Subtract the number of electrons consumed for forming single bonds from the total valence e−
Step 4 - Distribute the remaining valence electrons as pairs around each terminal atom so that each atom attains octet of e−
H requires duet or duplet of e−
Chemical Bonding Molecular Structure L-1
Drawing lewis structures
Step 5 - Match the number af electrons distributed to the number of valence electron counted in step 1
Chemical Bonding Molecular Structure L-1 Chemical bonding and molecular structure $\rightarrow$ $\rightarrow$ Chemical bonding and molecular structure $\rightarrow$ Chemical bonds $\rightarrow$ Chemical bonds