Slide 1: Introduction

  • Resistivity is a fundamental property of materials related to their ability to conduct electricity.
  • It determines how easily electric current flows through a material.
  • Resistivity is denoted by the symbol ρ (rho).
  • In this lecture, we will discuss the mobility and temperature dependence of resistivity.

Slide 2: Definition of Resistivity

  • Resistivity is a measure of the resistance of a material to the flow of electric current.
  • It is defined as the ratio of the electric field (E) applied to a material to the current density (J) it produces.
  • Mathematically, resistivity (ρ) is given by ρ = E/J.
  • The SI unit of resistivity is ohm-meter (Ω·m).

Slide 3: Mobility

  • Mobility refers to the ability of charge carriers (electrons or holes) to move through a material in the presence of an electric field.
  • It is denoted by the symbol μ (mu) and is measured in square meters per volt-second (m2/V·s).
  • Mobility is a characteristic property of charge carriers in a material.

Slide 4: Drift Velocity

  • In the presence of an electric field, charge carriers experience a force that causes them to move.
  • The average velocity with which charge carriers drift in a particular direction is called drift velocity (v).
  • Drift velocity is directly proportional to the electric field strength and mobility.
  • Mathematically, v = μE, where E is the electric field strength.

Slide 5: Conductivity

  • Conductivity (σ) is the reciprocal of resistivity and is a measure of how well a material conducts electricity.
  • It indicates the ease with which charge carriers can move through a material.
  • Mathematically, conductivity is given by σ = 1/ρ.
  • The SI unit of conductivity is Siemens per meter (S/m).

Slide 6: Relation between Resistivity and Conductivity

  • Resistivity (ρ) and conductivity (σ) are related by the equation σ = 1/ρ.
  • In other words, conductivity is the inverse of resistivity, and vice versa.
  • Materials with high conductivity have low resistivity, and vice versa.

Slide 7: Temperature Dependence of Resistivity

  • The resistivity of most materials changes with temperature.
  • For most metals, the resistivity increases with increasing temperature.
  • This is because as temperature rises, the atoms in the material vibrate more and impede the motion of charge carriers.
  • On the other hand, the resistivity of some semiconductors decreases with increasing temperature.

Slide 8: Temperature Coefficient of Resistivity

  • The rate of change of resistivity with temperature is quantified by the temperature coefficient of resistivity (α).
  • It is defined as α = (1/ρ) * (dρ/dT), where ρ is the resistivity and T is the temperature.
  • The unit of temperature coefficient of resistivity is per degree Celsius (Ω·m/°C) or per Kelvin (Ω·m/K).

Slide 9: Positive Temperature Coefficient of Resistivity

  • Materials with a positive temperature coefficient of resistivity (PTC) have their resistivity increase with temperature.
  • Most metals exhibit a positive temperature coefficient.
  • Examples: Copper, aluminum, silver.

Slide 10: Negative Temperature Coefficient of Resistivity

  • Materials with a negative temperature coefficient of resistivity (NTC) have their resistivity decrease with temperature.
  • Some semiconductors exhibit a negative temperature coefficient.
  • Example: Silicon, germanium.

Slide 11: Mobility and Temperature Dependence of Resistivity

  • In materials, the mobility of charge carriers plays a crucial role in determining resistivity.
  • The mobility of electrons (μe) and the mobility of holes (μh) may have different values.
  • The total current density (J) in a material depends on the mobility of both electrons and holes.
  • The average drift velocity (v) of charge carriers also depends on their respective mobilities.

Slide 12: Drift Velocity and Mobility

  • The drift velocity (v) of charge carriers is related to their mobility (μ) by the equation v = μE.
  • A higher mobility implies that charge carriers can move more efficiently under the influence of an electric field.
  • Materials with higher mobilities tend to have lower resistivities and higher conductivities.

Slide 13: Factors Affecting Mobility

  • The mobility of charge carriers in a material depends on various factors, including:
    • Crystal structure and lattice defects.
    • Temperature.
    • Presence of impurities or doping.
    • Electric field strength.

Slide 14: Temperature Dependence of Mobility

  • The mobility of charge carriers in a material typically decreases with increasing temperature.
  • As temperature rises, lattice vibrations increase, causing more collisions between charge carriers and lattice atoms.
  • These collisions impede the motion of charge carriers, resulting in a decrease in mobility.

Slide 15: Example of Temperature Dependence of Mobility

  • In a pure semiconductor such as silicon, the mobility of electrons decreases with increasing temperature.
  • At low temperatures, the mobility is relatively high, leading to efficient charge transport.
  • However, as temperature increases, lattice vibrations impede the motion of electrons, reducing their mobility.

Slide 16: Variation of Resistivity with Temperature

  • For most metals, resistivity increases with increasing temperature.
  • This is due to the increased lattice vibrations, which impede the flow of electrons.
  • The temperature coefficient of resistivity (α) quantifies this increase in resistivity with temperature.

Slide 17: Temperature Coefficient of Resistivity (α)

  • The temperature coefficient of resistivity (α) is given by α = (1/ρ) * (dρ/dT).
  • It measures the rate of change of resistivity (ρ) with respect to temperature (T).
  • The sign of the temperature coefficient indicates whether the resistivity increases or decreases with temperature.

Slide 18: Example of Positive Temperature Coefficient

  • Copper, a common metal, exhibits a positive temperature coefficient of resistivity.
  • As temperature increases, the resistivity of copper increases.
  • This is due to the increased lattice vibrations that impede the motion of electrons, resulting in higher resistance.

Slide 19: Example of Negative Temperature Coefficient

  • Germanium, a semiconductor, exhibits a negative temperature coefficient of resistivity.
  • As temperature increases, the resistivity of germanium decreases.
  • This is because higher temperatures create more charge carriers, increasing conductivity and decreasing resistance.

Slide 20: Applications of Mobility and Temperature Dependence of Resistivity

  • Understanding the mobility and temperature dependence of resistivity is crucial in many practical applications, including:
    • Designing electronic devices and circuits.
    • Thermal management of electrical components.
    • Materials selection for specific temperature ranges and operating conditions.
    • Optimizing energy efficiency in electrical systems.

Slide 21: Mobility and Temperature Dependence of Resistivity

  • The mobility of charge carriers plays a crucial role in determining the resistivity of a material.
  • The mobility of electrons (μe) and holes (μh) can have different values.
  • The resistivity of a material depends on the mobility of both electrons and holes.
  • The drift velocity of charge carriers also depends on their respective mobilities.
  • Temperature affects the mobility of charge carriers and thus, the resistivity of a material.

Slide 22: Drift Velocity and Mobility

  • The drift velocity (v) of charge carriers is related to their mobility (μ) by the equation v = μE.
  • Higher mobility allows charge carriers to move more efficiently under an electric field.
  • Materials with higher mobilities tend to have lower resistivities and higher conductivities.
  • The mobility of charge carriers can be influenced by factors such as crystal structure, temperature, doping, and electric field strength.
  • In general, higher temperatures reduce the mobility of charge carriers.

Slide 23: Factors Affecting Mobility

  • Crystal structure and lattice defects can affect charge carrier mobility.
  • Temperature influences lattice vibrations, affecting the mobility of charge carriers.
  • The presence of impurities or doping can alter the mobility of charge carriers.
  • Electric field strength can impact the mobility of charge carriers in a material.
  • Optimizing these factors is essential for improving the electrical conductivity of materials.

Slide 24: Temperature Dependence of Mobility

  • The mobility of charge carriers typically decreases with increasing temperature.
  • As temperature rises, lattice vibrations increase, leading to more collisions between charge carriers and lattice atoms.
  • These collisions impede the motion of charge carriers and reduce their mobility.
  • For metals and most semiconductors, higher temperatures result in decreased mobility.
  • Temperature control is important in maintaining the desired electrical properties of materials.

Slide 25: Example of Temperature Dependence of Mobility

  • Silicon, a commonly used semiconductor, exhibits a decrease in mobility with increasing temperature.
  • At low temperatures, the mobility of electrons in silicon is relatively high, facilitating efficient charge transport.
  • However, as temperature increases, lattice vibrations hinder the motion of electrons, causing a decrease in mobility.

Slide 26: Variation of Resistivity with Temperature

  • The resistivity of most metals increases with increasing temperature.
  • This is due to the increased lattice vibrations, which impede the flow of charge carriers.
  • The temperature coefficient of resistivity (α) quantifies this increase in resistivity.
  • The temperature coefficient is defined as α = (1/ρ) * (dρ/dT), where ρ is the resistivity and T is the temperature.
  • A positive α indicates an increase in resistivity with temperature.

Slide 27: Temperature Coefficient of Resistivity (α)

  • The temperature coefficient of resistivity (α) measures the rate of change of resistivity with respect to temperature.
  • It is expressed in units of ohm-meter per degree Celsius (Ω·m/°C) or ohm-meter per Kelvin (Ω·m/K).
  • A positive α indicates that resistivity increases with increasing temperature.
  • A negative α indicates that resistivity decreases with increasing temperature.
  • The temperature coefficient provides valuable information for materials selection and designing electrical systems.

Slide 28: Example of Positive Temperature Coefficient

  • Copper, a commonly used metal, exhibits a positive temperature coefficient of resistivity.
  • As temperature increases, the resistivity of copper also increases.
  • This is because higher temperatures result in increased lattice vibrations, hindering the motion of electrons and increasing resistance.

Slide 29: Example of Negative Temperature Coefficient

  • Germanium, a semiconductor material, exhibits a negative temperature coefficient of resistivity.
  • As temperature increases, the resistivity of germanium decreases.
  • This is due to the generation of more charge carriers at higher temperatures, resulting in increased conductivity and decreased resistance.

Slide 30: Applications of Mobility and Temperature Dependence of Resistivity

  • Understanding mobility and the temperature dependence of resistivity is important in various practical applications, including:
    • Designing electronic devices and circuits with desired electrical properties.
    • Thermal management of electrical components to prevent temperature-induced changes in resistivity.
    • Selecting appropriate materials for specific temperature ranges and operating conditions.
    • Optimizing energy efficiency in electrical systems by controlling resistivity and conductivity.
    • Developing advanced materials for electronic applications based on their resistivity characteristics.