Slide 1: Conductors, Semiconductors and Insulators - INTRODUCTION

  • In solid-state physics, materials are classified into three categories based on their electrical conductivity: conductors, semiconductors, and insulators.
  • Conductors are materials that allow electric current to flow easily. They have a high number of free electrons that are available to move in the presence of an electric field.
  • Semiconductors have intermediate conductivity, with a number of free electrons between that of conductors and insulators. They can be modified to act as conductors or insulators by controlling the doping level or temperature.
  • Insulators have very low conductivity and do not allow the flow of electric current. They have a completely filled valence band and a large band gap between the valence and conduction bands.

Slide 2: Conductors

  • Conductors have a high number of free electrons in their conduction band.
  • In metals, the valence band is partially filled, which allows the electrons to move freely and conduct electricity.
  • Examples of good conductors include copper, aluminum, silver, and gold.
  • Conductors also have low resistance, which means they dissipate very little energy in the form of heat.
  • The conductivity of a conductor can be increased by decreasing its length, increasing its cross-sectional area, or using materials with higher conductivity.

Slide 3: Semiconductors

  • Unlike conductors, semiconductors have a smaller number of free electrons in their conduction band.
  • The valence band is partially filled, but the conduction band is partially empty.
  • The conductivity of semiconductors can be modified by doping, which involves adding impurity atoms to the crystal lattice.
  • Two types of doping are commonly used: n-type doping (adding atoms with extra electrons) and p-type doping (adding atoms with missing electrons).
  • Silicon and germanium are widely used semiconductors.

Slide 4: Insulators

  • Insulators have a completely filled valence band and a large energy gap between the valence and conduction bands.
  • This energy gap is so large that electrons cannot gain enough energy to jump to the conduction band, making insulators poor conductors of electricity.
  • Examples of insulators include rubber, glass, wood, and plastic.
  • Insulators are widely used for electrical insulation, preventing the flow of current where it is not desired.
  • Insulators can be damaged if subjected to high voltages or temperatures.

Slide 5: Conductivity and Resistivity

  • Conductivity (σ) is a measure of a material’s ability to conduct electric current.
  • It is the reciprocal of resistivity (ρ), which is a measure of the opposition offered by a material to the flow of electric current.
  • The SI unit of conductivity is siemens per meter (S/m), and the SI unit of resistivity is ohm-meter (Ω.m).
  • Conductivity and resistivity are related by the equation: σ = 1/ρ.
  • Materials with high conductivity have low resistivity, allowing electric current to flow easily.

Slide 6: Band Theory of Solids

  • The behavior of conductors, semiconductors, and insulators can be explained using the band theory of solids.
  • According to this theory, electrons in solids are distributed in energy bands: the valence band and the conduction band.
  • The valence band is the highest energy band that contains electrons at absolute zero temperature.
  • The conduction band is the energy band above the valence band, and it is empty at absolute zero temperature.
  • The band gap is the energy difference between the valence and conduction bands.

Slide 7: Valence Band and Conduction Band

  • In conductors, the valence band is partially filled, and there is no or a small band gap between the valence and conduction bands.
  • In semiconductors, the valence band is partially filled, and there is a small band gap between the valence and conduction bands.
  • In insulators, the valence band is completely filled, and there is a large energy gap (band gap) between the valence and conduction bands.
  • Electrons in the valence band are tightly bound to their respective atoms, while electrons in the conduction band are free to move.

Slide 8: Effect of Temperature on Conductivity

  • As temperature increases, the conductivity of conductors generally decreases due to increased scattering of free electrons.
  • Semiconductors show an increase in conductivity with temperature due to the increased number of thermally excited electrons.
  • Insulators also have an increase in conductivity with temperature, but it is much smaller compared to semiconductors.
  • At extremely high temperatures, semiconductors can become conductors, and insulators can become semiconductors.

Slide 9: Examples of Applications

  • Conductors find applications in electrical wiring, electric circuits, and in the construction of electrical devices.
  • Semiconductors are commonly used in electronic devices such as transistors, diodes, and integrated circuits.
  • Insulators are used for electrical safety, insulation of wires, and the construction of insulating materials such as electrical cables and insulating coatings.
  • The classification of materials into conductors, semiconductors, and insulators is crucial for understanding and designing electronic devices.

Slide 10: Summary

  • Conductors, semiconductors, and insulators are categories of materials based on their electrical conductivity.
  • Conductors have high conductivity, semiconductors have intermediate conductivity, and insulators have low conductivity.
  • Conductivity is determined by the number of free electrons and their ability to move in the presence of an electric field.
  • The behavior of materials can be explained using the band theory of solids, which involves the valence band, conduction band, and band gap.
  • The classification of materials is essential in various applications, including electrical wiring, electronic devices, and insulation.
  1. Conductivity and Resistivity
  • Conductivity is a measure of a material’s ability to conduct electric current.
  • Resistivity is a measure of the opposition offered by a material to the flow of electric current.
  • Conductivity and resistivity are inversely related: σ = 1/ρ.
  • Conductivity is expressed in siemens per meter (S/m).
  • Resistivity is expressed in ohm-meter (Ω·m).
  1. Factors Affecting Conductivity
  • Temperature: Conductivity generally decreases with increasing temperature due to increased electron scattering.
  • Cross-sectional Area: Increasing the cross-sectional area of a conductor increases its conductivity.
  • Length: Decreasing the length of a conductor increases its conductivity.
  • Material Selection: Materials with higher conductivity have higher overall conductivity.
  1. Factors Affecting Resistivity
  • Temperature: Resistivity generally increases with increasing temperature due to increased atomic vibrations.
  • Impurities: Impurities in a material can increase resistivity by disrupting the regular crystal lattice.
  • Alloys: Alloys can have lower resistivity compared to pure metals, making them better conductors.
  • Material Properties: Resistivity is an inherent property of a material and depends on its atomic structure.
  1. Ohm’s Law
  • Ohm’s Law states that the current passing through a conductor is directly proportional to the voltage applied, and inversely proportional to the resistance.
  • Mathematically, Ohm’s Law can be expressed as: V = IR, where V is the voltage, I is the current, and R is the resistance.
  • This law applies to conductors that obey Ohm’s Law, which includes most metallic conductors at normal temperatures.
  1. Power in Electric Circuits
  • The power dissipated in a resistor can be calculated using the equation: P = IV, where P is the power, I is the current, and V is the voltage across the resistor.
  • Power is measured in watts (W).
  • In a circuit, power can be transferred from one component to another, or it can be dissipated as heat in resistors.
  • Understanding power is crucial for designing circuits and optimizing energy usage.
  1. Superconductivity
  • Superconductivity is a phenomenon where certain materials exhibit zero electrical resistance at very low temperatures.
  • Superconductors can conduct electric current indefinitely without any energy loss.
  • Below a critical temperature called the superconducting transition temperature (Tc), a superconductor exhibits superconducting properties.
  • Superconductors have numerous applications, including in energy transmission, magnetic levitation, and particle accelerators.
  1. Band Gap in Semiconductors
  • Semiconductors have a band gap, which is the energy difference between the valence band and the conduction band.
  • The band gap determines whether a material is a semiconductor or an insulator.
  • Intrinsic semiconductors have a small band gap and can be modified through doping.
  • Doping introduces impurities to increase either the number of free electrons (n-type) or the number of holes (p-type) in the material.
  1. Doping in Semiconductors
  • Doping is the intentional introduction of impurity atoms into a semiconductor crystal lattice.
  • N-type doping involves adding atoms with extra electrons, such as phosphorus or arsenic, which become the majority carriers.
  • P-type doping involves adding atoms with missing electrons, such as boron or gallium, which create holes as the majority carriers.
  • Doping changes the conductivity and electrical properties of semiconductors, making them suitable for various electronic devices.
  1. PN Junction Diode
  • A PN junction diode is a basic semiconducting device formed by joining a p-type semiconductor with an n-type semiconductor.
  • The p-side of the diode is called the anode, and the n-side is called the cathode.
  • The PN junction diode allows current to flow in one direction (forward biased) but blocks current in the opposite direction (reverse biased).
  • It has various applications, such as rectification, signal modulation, and voltage regulation.
  1. Summary
  • Conductivity and resistivity are key properties of materials that determine their ability to conduct electric current.
  • Factors affecting conductivity include temperature, cross-sectional area, length, and material selection.
  • Factors affecting resistivity include temperature, impurities, alloys, and material properties.
  • Ohm’s Law relates voltage, current, and resistance in a conductor.
  • Power in electric circuits is calculated using P = IV.
  • Superconductivity is a phenomenon with zero electrical resistance at low temperatures.
  • Semiconductors have a band gap and can be modified through doping and used in electronic devices.
  • PN junction diodes have applications in rectification, modulation, and voltage regulation.

Slide 21: Energy Band Diagram

  • Energy band diagrams are used to visualize the energy levels of electrons in a solid.
  • The horizontal axis represents the position in the material, while the vertical axis represents the energy level.
  • The valence band is the lower energy level occupied by electrons, while the conduction band is the higher energy level that can be occupied by electrons.
  • The band gap is the energy difference between the valence and conduction bands.

Slide 22: Conductivity in Metals

  • The high conductivity of metals is due to the presence of a partially filled valence band and overlapping conduction bands.
  • Electrons in the valence band are loosely held and can easily move in response to an electric field.
  • These electrons are referred to as free electrons, and they contribute to the overall conductivity of the metal.
  • The high density of free electrons in metals results in their high conductivity.

Slide 23: Intrinsic Semiconductors

  • Intrinsic semiconductors are pure semiconducting materials without any intentional doping.
  • They have a small band gap that requires an input of energy to promote electrons from the valence band to the conduction band.
  • At absolute zero temperature, intrinsic semiconductors have very few free electrons in the conduction band.
  • However, as the temperature increases, thermal energy excites some electrons into the conduction band, increasing the conductivity.

Slide 24: Extrinsic Semiconductors - N-type

  • N-type semiconductors are created by doping the intrinsic semiconductor with impurity atoms that have more valence electrons.
  • Examples of impurity atoms used for n-type doping are phosphorus, arsenic, and antimony.
  • These impurity atoms introduce additional electrons into the material, creating an excess of negative charges.
  • The extra electrons in n-type semiconductors become the majority carriers and significantly increase the conductivity.

Slide 25: Extrinsic Semiconductors - P-type

  • P-type semiconductors are created by doping the intrinsic semiconductor with impurity atoms that have fewer valence electrons.
  • Examples of impurity atoms used for p-type doping are boron, aluminum, and gallium.
  • These impurity atoms create a deficiency of electrons, known as holes, in the semiconductor crystal lattice.
  • The holes in p-type semiconductors become the majority carriers and contribute to the conductivity.

Slide 26: PN Junction and Diode Operation

  • A PN junction is formed when a p-type semiconductor is brought into contact with an n-type semiconductor.
  • This junction forms a depletion region due to the migration of free electrons and holes across the junction.
  • When a forward bias voltage is applied, the depletion region decreases, allowing current flow through the diode.
  • In reverse bias voltage, the depletion region widens, preventing significant current flow through the diode.

Slide 27: Diode Characteristics

  • The current-voltage (IV) characteristics of a diode exhibit different behaviors depending on the bias voltage.
  • For forward bias, the diode has a low resistance, and current flows easily.
  • For reverse bias, the diode has a very high resistance, and only a small leakage current is present.
  • The forward voltage drop across a diode is usually around 0.7 V for silicon diodes and 0.3 V for germanium diodes.

Slide 28: Semiconductor Devices

  • Semiconductors are the foundation of modern electronic devices.
  • Transistors are the building blocks of digital electronics and amplifiers.
  • Diodes are used for rectification, voltage regulation, and signal modulation.
  • Integrated circuits (ICs) are made up of numerous semiconductor devices on a single chip and are used in various applications, including computers, smartphones, and electronic systems.

Slide 29: Applications of Insulators

  • Insulators have very low conductivity and are used to prevent the flow of electric current.
  • Insulators are widely used in electrical systems for insulation and safety, such as in electrical cables, switches, and insulation materials.
  • They provide protection against electric shocks and minimize energy loss.
  • Insulators can be made from a variety of materials, including rubber, plastic, glass, and ceramic.

Slide 30: Summary

  • Energy band diagrams help visualize the energy levels of electrons in solids.
  • Conductivity in metals is due to the presence of free electrons in the valence and conduction bands.
  • Intrinsic semiconductors have a small band gap and require thermal energy to promote electron movement.
  • Extrinsic semiconductors, such as n-type and p-type, are created through intentional doping.
  • The PN junction creates a diode with specific operational characteristics.
  • Semiconductors play a crucial role in various electronic devices and integrated circuits.
  • Insulators have low conductivity and are used for electrical insulation and safety purposes.