Slide 1: Isolation of Metals
Definition of isolation of metals
Importance of metal isolation processes
Key concepts:
Ore
Gangue
Concentration
Calcination
Roasting
Slide 2: Examples of Common Metals
Iron (Fe)
Aluminium (Al)
Copper (Cu)
Zinc (Zn)
Silver (Ag)
Gold (Au)
Lead (Pb)
Tin (Sn)
Mercury (Hg)
Slide 3: Types of Ores
Definition of ore
Types of ores:
Oxides
Sulphides
Carbonates
Halides
Iron extraction flowchart
Steps involved in the extraction of iron:
Crushing and grinding the ore
Concentration of the ore
Calcination
Smelting
Refining
Aluminium extraction flowchart
Steps involved in the extraction of aluminium:
Crushing and grinding the ore
Digestion or leaching of the ore
Concentration of the ore
Electrolytic reduction of aluminium oxide
Purification of aluminium
Copper extraction flowchart
Steps involved in the extraction of copper:
Crushing and grinding the ore
Concentration of the ore
Roasting
Smelting
Refining
Zinc extraction flowchart
Steps involved in the extraction of zinc:
Crushing and grinding the ore
Concentration of the ore
Roasting
Smelting
Refining
Silver extraction flowchart
Steps involved in the extraction of silver:
Crushing and grinding the ore
Concentration of the ore
Roasting
Smelting
Refining
Gold extraction flowchart
Steps involved in the extraction of gold:
Crushing and grinding the ore
Concentration of the ore
Roasting
Smelting
Refining
Lead extraction flowchart
Steps involved in the extraction of lead:
Crushing and grinding the ore
Concentration of the ore
Roasting
Smelting
Refining
Physical Properties of Metals
High electrical and thermal conductivity
Malleability and ductility
Lustre and reflectivity
High melting and boiling points
Solid state at room temperature (except mercury)
Good conductors of heat and electricity
Chemical Properties of Metals
Reactivity with oxygen: Examples include rusting of iron and tarnishing of silver
Reaction with acids: Metals react with acids to produce salts and hydrogen gas
Reaction with water: Some metals react with water to form metal oxides or hydroxides and hydrogen gas
Reactivity series: Arrangement of metals in a decreasing order of their reactivity
Displacement Reactions
Definition of a displacement reaction
The more reactive metal displaces the less reactive metal from its compound
Example: Zinc displaces copper from copper sulfate solution
Zn(s) + CuSO4(aq) -> ZnSO4(aq) + Cu(s)
Acid-Base Reactions Involving Metals
Reaction of metals with bases: Metals react with bases to produce metal hydroxides and hydrogen gas
Reaction of metals with metal salts: Metals react with metal salts to produce another metal and a salt solution
Metal Oxides and Metal Hydroxides
Formation of metal oxides: Metals combine with oxygen to form metal oxides
Formation of metal hydroxides: Metals react with water to form metal hydroxides
Example: Sodium oxide + water -> Sodium hydroxide
Metal Carbonates and Hydrogencarbonates
Reaction of metals with carbonates: Metals react with carbonates to form metal oxides and carbon dioxide gas
Reaction of metals with hydrogencarbonates: Metals react with hydrogencarbonates to form metal carbonates, water, and carbon dioxide gas
Reactivity Series of Metals
Definition of the reactivity series
Arrangement of metals in a decreasing order of their reactivity
Importance of the reactivity series in predicting displacement reactions
Extraction of Metals using Electrolysis
Definition of electrolysis
Extraction of metals like sodium, aluminium, and magnesium using electrolysis
Electrolysis of molten compounds and aqueous solutions
Redox Reactions involving Metals
Definition of redox reactions
Examples of redox reactions involving metals:
Formation of metal oxide from Metal + Oxygen
Reaction of metal with acid
Reaction of metal with water
Displacement reactions
Environmental Impact of Metal Extraction
Environmental issues caused by mining and metal extraction
Pollution of air, water, and soil
Efforts to reduce environmental impact: Recycling and sustainable extraction methods
Properties of Metalloids
Metalloids have properties intermediate between metals and nonmetals
They have both metallic and nonmetallic characteristics
Examples of metalloids: Silicon (Si), Germanium (Ge), Arsenic (As), Antimony (Sb), Tellurium (Te)
Chemical Properties of Metalloids
Metalloids can form both positive and negative ions
They can act as both conductors and insulators of electricity
They exhibit varying reactivity with acids and bases
Metalloids can form covalent compounds with nonmetals
Applications of Metalloids
Silicon: Used in the production of semiconductors and computer chips
Germanium: Used in infrared optics, fiber optic communication, and solar cells
Arsenic: Used in wood preservation, pesticides, and in electronic devices
Antimony: Used in flame retardants, batteries, and as an alloying agent
Tellurium: Used in solar panels, thermoelectric devices, and in alloys for metals
Extraction of Metalloids from Ores
Metalloids are usually extracted from their ores using a combination of pyrometallurgical and hydrometallurgical methods
The ore is first crushed and then subjected to roasting or smelting processes
The resulting metalloid compound is then purified through chemical processes such as leaching or electrolysis
Reactivity of Nonmetals
Nonmetals tend to have high ionization energies and electronegativities
Nonmetals generally do not form positively charged ions (cations)
Nonmetals can form negative ions (anions) by gaining electrons
The reactivity of nonmetals varies depending on their position in the periodic table
Physical Properties of Nonmetals
Nonmetals are generally poor conductors of heat and electricity
Nonmetals are brittle and can be in solid, liquid, or gaseous states at room temperature
Nonmetals have low melting and boiling points compared to metals
Chemical Properties of Nonmetals
Nonmetals tend to gain electrons during chemical reactions
Nonmetals can react with metals to form ionic compounds
Nonmetals can react with other nonmetals to form covalent compounds
Nonmetals can react with oxygen to form oxides, many of which are acidic in nature
Importance of Nonmetals in Daily Life
Oxygen: Essential for respiration and combustion
Carbon: Forms the basis of organic compounds and is present in all living organisms
Nitrogen: Key component in DNA, proteins, and fertilizers
Hydrogen: Used in the production of ammonia, petroleum refining, and as an energy carrier
Chlorine: Used as a disinfectant, in the production of PVC, and in water treatment
Noble Gases - Properties and Applications
Noble gases have full valence electron shells and are chemically stable
They are inert and do not readily form compounds with other elements
Examples of noble gases: Helium (He), Neon (Ne), Argon (Ar), Krypton (Kr), Xenon (Xe), Radon (Rn)
Applications of noble gases include lighting, lasers, cryogenics, and as an inert atmosphere in scientific research
Summary and Recap
Recap of key concepts covered in the lecture:
Isolation of metals and metalloids from ores
Properties and chemical reactions of metalloids and nonmetals
Importance and applications of nonmetals in daily life
Properties and applications of noble gases
Emphasize the importance of understanding the properties and behavior of metals, metalloids, and nonmetals in various industries and everyday life
Resume presentation
Slide 1: Isolation of Metals Definition of isolation of metals Importance of metal isolation processes Key concepts: Ore Gangue Concentration Calcination Roasting