- Definition of isolation of metals
- Importance of metal isolation processes
- Key concepts:
- Ore
- Gangue
- Concentration
- Calcination
- Roasting
- Iron (Fe)
- Aluminium (Al)
- Copper (Cu)
- Zinc (Zn)
- Silver (Ag)
- Gold (Au)
- Lead (Pb)
- Tin (Sn)
- Mercury (Hg)
Slide 3: Types of Ores
- Definition of ore
- Types of ores:
- Oxides
- Sulphides
- Carbonates
- Halides
- Iron extraction flowchart
- Steps involved in the extraction of iron:
- Crushing and grinding the ore
- Concentration of the ore
- Calcination
- Smelting
- Refining
- Aluminium extraction flowchart
- Steps involved in the extraction of aluminium:
- Crushing and grinding the ore
- Digestion or leaching of the ore
- Concentration of the ore
- Electrolytic reduction of aluminium oxide
- Purification of aluminium
- Copper extraction flowchart
- Steps involved in the extraction of copper:
- Crushing and grinding the ore
- Concentration of the ore
- Roasting
- Smelting
- Refining
- Zinc extraction flowchart
- Steps involved in the extraction of zinc:
- Crushing and grinding the ore
- Concentration of the ore
- Roasting
- Smelting
- Refining
- Silver extraction flowchart
- Steps involved in the extraction of silver:
- Crushing and grinding the ore
- Concentration of the ore
- Roasting
- Smelting
- Refining
- Gold extraction flowchart
- Steps involved in the extraction of gold:
- Crushing and grinding the ore
- Concentration of the ore
- Roasting
- Smelting
- Refining
- Lead extraction flowchart
- Steps involved in the extraction of lead:
- Crushing and grinding the ore
- Concentration of the ore
- Roasting
- Smelting
- Refining
- Physical Properties of Metals
- High electrical and thermal conductivity
- Malleability and ductility
- Lustre and reflectivity
- High melting and boiling points
- Solid state at room temperature (except mercury)
- Good conductors of heat and electricity
- Chemical Properties of Metals
- Reactivity with oxygen: Examples include rusting of iron and tarnishing of silver
- Reaction with acids: Metals react with acids to produce salts and hydrogen gas
- Reaction with water: Some metals react with water to form metal oxides or hydroxides and hydrogen gas
- Reactivity series: Arrangement of metals in a decreasing order of their reactivity
- Displacement Reactions
- Definition of a displacement reaction
- The more reactive metal displaces the less reactive metal from its compound
- Example: Zinc displaces copper from copper sulfate solution
- Zn(s) + CuSO4(aq) -> ZnSO4(aq) + Cu(s)
- Acid-Base Reactions Involving Metals
- Reaction of metals with bases: Metals react with bases to produce metal hydroxides and hydrogen gas
- Reaction of metals with metal salts: Metals react with metal salts to produce another metal and a salt solution
- Metal Oxides and Metal Hydroxides
- Formation of metal oxides: Metals combine with oxygen to form metal oxides
- Formation of metal hydroxides: Metals react with water to form metal hydroxides
- Example: Sodium oxide + water -> Sodium hydroxide
- Metal Carbonates and Hydrogencarbonates
- Reaction of metals with carbonates: Metals react with carbonates to form metal oxides and carbon dioxide gas
- Reaction of metals with hydrogencarbonates: Metals react with hydrogencarbonates to form metal carbonates, water, and carbon dioxide gas
- Reactivity Series of Metals
- Definition of the reactivity series
- Arrangement of metals in a decreasing order of their reactivity
- Importance of the reactivity series in predicting displacement reactions
- Extraction of Metals using Electrolysis
- Definition of electrolysis
- Extraction of metals like sodium, aluminium, and magnesium using electrolysis
- Electrolysis of molten compounds and aqueous solutions
- Redox Reactions involving Metals
- Definition of redox reactions
- Examples of redox reactions involving metals:
- Formation of metal oxide from Metal + Oxygen
- Reaction of metal with acid
- Reaction of metal with water
- Displacement reactions
- Environmental Impact of Metal Extraction
- Environmental issues caused by mining and metal extraction
- Pollution of air, water, and soil
- Efforts to reduce environmental impact: Recycling and sustainable extraction methods
- Properties of Metalloids
- Metalloids have properties intermediate between metals and nonmetals
- They have both metallic and nonmetallic characteristics
- Examples of metalloids: Silicon (Si), Germanium (Ge), Arsenic (As), Antimony (Sb), Tellurium (Te)
- Chemical Properties of Metalloids
- Metalloids can form both positive and negative ions
- They can act as both conductors and insulators of electricity
- They exhibit varying reactivity with acids and bases
- Metalloids can form covalent compounds with nonmetals
- Applications of Metalloids
- Silicon: Used in the production of semiconductors and computer chips
- Germanium: Used in infrared optics, fiber optic communication, and solar cells
- Arsenic: Used in wood preservation, pesticides, and in electronic devices
- Antimony: Used in flame retardants, batteries, and as an alloying agent
- Tellurium: Used in solar panels, thermoelectric devices, and in alloys for metals
- Extraction of Metalloids from Ores
- Metalloids are usually extracted from their ores using a combination of pyrometallurgical and hydrometallurgical methods
- The ore is first crushed and then subjected to roasting or smelting processes
- The resulting metalloid compound is then purified through chemical processes such as leaching or electrolysis
- Reactivity of Nonmetals
- Nonmetals tend to have high ionization energies and electronegativities
- Nonmetals generally do not form positively charged ions (cations)
- Nonmetals can form negative ions (anions) by gaining electrons
- The reactivity of nonmetals varies depending on their position in the periodic table
- Physical Properties of Nonmetals
- Nonmetals are generally poor conductors of heat and electricity
- Nonmetals are brittle and can be in solid, liquid, or gaseous states at room temperature
- Nonmetals have low melting and boiling points compared to metals
- Chemical Properties of Nonmetals
- Nonmetals tend to gain electrons during chemical reactions
- Nonmetals can react with metals to form ionic compounds
- Nonmetals can react with other nonmetals to form covalent compounds
- Nonmetals can react with oxygen to form oxides, many of which are acidic in nature
- Importance of Nonmetals in Daily Life
- Oxygen: Essential for respiration and combustion
- Carbon: Forms the basis of organic compounds and is present in all living organisms
- Nitrogen: Key component in DNA, proteins, and fertilizers
- Hydrogen: Used in the production of ammonia, petroleum refining, and as an energy carrier
- Chlorine: Used as a disinfectant, in the production of PVC, and in water treatment
- Noble Gases - Properties and Applications
- Noble gases have full valence electron shells and are chemically stable
- They are inert and do not readily form compounds with other elements
- Examples of noble gases: Helium (He), Neon (Ne), Argon (Ar), Krypton (Kr), Xenon (Xe), Radon (Rn)
- Applications of noble gases include lighting, lasers, cryogenics, and as an inert atmosphere in scientific research
- Summary and Recap
- Recap of key concepts covered in the lecture:
- Isolation of metals and metalloids from ores
- Properties and chemical reactions of metalloids and nonmetals
- Importance and applications of nonmetals in daily life
- Properties and applications of noble gases
- Emphasize the importance of understanding the properties and behavior of metals, metalloids, and nonmetals in various industries and everyday life