Electrochemistry - Specific Conductance

  • Introduction to Electrochemistry
  • Definition of Specific Conductance
  • Factors Affecting Specific Conductance
  • Measurement of Specific Conductance
  • Units of Specific Conductance

Introduction to Electrochemistry

  • Electrochemistry is the branch of chemistry that deals with the study of electrically charged particles and their chemical reactions.
  • It involves the processes of oxidation and reduction.
  • Electrochemical reactions involve the transfer of electrons between species.

Definition of Specific Conductance

  • Specific conductance, also known as conductivity, is a measure of a solution’s ability to conduct an electric current.
  • It is defined as the reciprocal of resistivity (ρ) and is denoted by the symbol ‘κ’ or ‘G’ (conductance).

Factors Affecting Specific Conductance

  • Concentration of ions: Higher concentration of ions leads to higher specific conductance.
  • Temperature: Increase in temperature generally increases the specific conductance.
  • Nature of solvent: Different solvents possess different conductivities.
  • Presence of impurities: Impurities in the solvent may affect the specific conductance.

Measurement of Specific Conductance

  • Conductivity can be measured using a conductometer or conductivity meter.
  • A cell with two electrodes is immersed in the solution, and the resistance is measured.
  • The resistance is then used to calculate the specific conductance.

Units of Specific Conductance

  • The SI unit of specific conductance is Siemens per meter (S/m).
  • Other common units include mho per centimeter (Ω^(-1)cm^(-1)) and millisiemens per centimeter (mS/cm).

Electrochemistry - Redox Reactions

  • Introduction to Redox Reactions
  • Oxidation and Reduction Definitions
  • Balancing Redox Equations
  • Half-Reactions and Redox Couples
  • Electrochemical Cells

Introduction to Redox Reactions

  • Redox reactions involve the transfer of electrons between species.
  • It stands for Reduction-Oxidation reactions.
  • Redox reactions play a crucial role in many chemical processes.

Oxidation and Reduction Definitions

  • Oxidation is the process of losing electrons, resulting in an increase in oxidation state.
  • Reduction is the process of gaining electrons, resulting in a decrease in oxidation state.

Balancing Redox Equations

  • Redox equations are balanced by ensuring that the number of electrons lost in oxidation is equal to the number of electrons gained in reduction.
  • Balancing can be done by the ion-electron method or oxidation number method.

Half-Reactions and Redox Couples

  • Half-reactions represent the individual oxidation or reduction reactions in a redox equation.
  • Redox couples refer to a pair of species that participate in a redox reaction.
  • Each species in a redox couple is represented with oxidation number and charge.

Electrochemical Cells

  • Electrochemical cells facilitate redox reactions.
  • They consist of two half-cells connected by a conductive material.
  • One half-cell contains the oxidizing agent, while the other half-cell contains the reducing agent.

Electrochemistry - Specific Conductance

  • Introduction to Electrochemistry
  • Definition of Specific Conductance
  • Factors Affecting Specific Conductance
  • Measurement of Specific Conductance
  • Units of Specific Conductance

Introduction to Electrochemistry

  • Electrochemistry is the branch of chemistry that deals with the study of electrically charged particles and their chemical reactions.
  • It involves the processes of oxidation and reduction.
  • Electrochemical reactions involve the transfer of electrons between species.

Definition of Specific Conductance

  • Specific conductance, also known as conductivity, is a measure of a solution’s ability to conduct an electric current.
  • It is defined as the reciprocal of resistivity (ρ) and is denoted by the symbol ‘κ’ or ‘G’ (conductance).

Factors Affecting Specific Conductance

  • Concentration of ions: Higher concentration of ions leads to higher specific conductance.
  • Temperature: Increase in temperature generally increases the specific conductance.
  • Nature of solvent: Different solvents possess different conductivities.
  • Presence of impurities: Impurities in the solvent may affect the specific conductance.

Measurement of Specific Conductance

  • Conductivity can be measured using a conductometer or conductivity meter.
  • A cell with two electrodes is immersed in the solution, and the resistance is measured.
  • The resistance is then used to calculate the specific conductance.

Units of Specific Conductance

  • The SI unit of specific conductance is Siemens per meter (S/m).
  • Other common units include mho per centimeter (Ω^(-1)cm^(-1)) and millisiemens per centimeter (mS/cm).

Electrochemistry - Redox Reactions

  • Introduction to Redox Reactions
  • Oxidation and Reduction Definitions
  • Balancing Redox Equations
  • Half-Reactions and Redox Couples
  • Electrochemical Cells

Introduction to Redox Reactions

  • Redox reactions involve the transfer of electrons between species.
  • It stands for Reduction-Oxidation reactions.
  • Redox reactions play a crucial role in many chemical processes.

Oxidation and Reduction Definitions

  • Oxidation is the process of losing electrons, resulting in an increase in oxidation state.
  • Reduction is the process of gaining electrons, resulting in a decrease in oxidation state.

Balancing Redox Equations

  • Redox equations are balanced by ensuring that the number of electrons lost in oxidation is equal to the number of electrons gained in reduction.
  • Balancing can be done by the ion-electron method or oxidation number method.

Half-Reactions and Redox Couples

  • Half-reactions represent the individual oxidation or reduction reactions in a redox equation.
  • Redox couples refer to a pair of species that participate in a redox reaction.
  • Each species in a redox couple is represented with oxidation number and charge.

Electrochemical Cells

  • Electrochemical cells facilitate redox reactions.
  • They consist of two half-cells connected by a conductive material.
  • One half-cell contains the oxidizing agent, while the other half-cell contains the reducing agent.

Electrochemistry - Specific Conductance

  • Introduction to Electrochemistry
  • Definition of Specific Conductance
  • Factors Affecting Specific Conductance
  • Measurement of Specific Conductance
  • Units of Specific Conductance

Introduction to Electrochemistry

  • Electrochemistry is the branch of chemistry that deals with the study of electrically charged particles and their chemical reactions.
  • It involves the processes of oxidation and reduction.
  • Electrochemical reactions involve the transfer of electrons between species.

Definition of Specific Conductance

  • Specific conductance, also known as conductivity, is a measure of a solution’s ability to conduct an electric current.
  • It is defined as the reciprocal of resistivity (ρ) and is denoted by the symbol ‘κ’ or ‘G’ (conductance).

Factors Affecting Specific Conductance

  • Concentration of ions: Higher concentration of ions leads to higher specific conductance.
  • Temperature: Increase in temperature generally increases the specific conductance.
  • Nature of solvent: Different solvents possess different conductivities.
  • Presence of impurities: Impurities in the solvent may affect the specific conductance.

Measurement of Specific Conductance

  • Conductivity can be measured using a conductometer or conductivity meter.
  • A cell with two electrodes is immersed in the solution, and the resistance is measured.
  • The resistance is then used to calculate the specific conductance.

Units of Specific Conductance

  • The SI unit of specific conductance is Siemens per meter (S/m).
  • Other common units include mho per centimeter (Ω^(-1)cm^(-1)) and millisiemens per centimeter (mS/cm).

Electrochemistry - Redox Reactions

  • Introduction to Redox Reactions
  • Oxidation and Reduction Definitions
  • Balancing Redox Equations
  • Half-Reactions and Redox Couples
  • Electrochemical Cells

Introduction to Redox Reactions

  • Redox reactions involve the transfer of electrons between species.
  • It stands for Reduction-Oxidation reactions.
  • Redox reactions play a crucial role in many chemical processes.

Oxidation and Reduction Definitions

  • Oxidation is the process of losing electrons, resulting in an increase in oxidation state.
  • Reduction is the process of gaining electrons, resulting in a decrease in oxidation state.

Balancing Redox Equations

  • Redox equations are balanced by ensuring that the number of electrons lost in oxidation is equal to the number of electrons gained in reduction.
  • Balancing can be done by the ion-electron method or oxidation number method.

Half-Reactions and Redox Couples

  • Half-reactions represent the individual oxidation or reduction reactions in a redox equation.
  • Redox couples refer to a pair of species that participate in a redox reaction.
  • Each species in a redox couple is represented with oxidation number and charge.

Electrochemical Cells

  • Electrochemical cells facilitate redox reactions.
  • They consist of two half-cells connected by a conductive material.
  • One half-cell contains the oxidizing agent, while the other half-cell contains the reducing agent.