Coordinate Compounds - Valence Bond Theory

  • Definition of coordinate compounds
  • Introduction to valence bond theory
  • Valence bond theory principles
    • Overlapping of atomic orbitals
    • Hybridization of atomic orbitals
    • Formation of localized bonds
  • Formation of coordinate bonds
  • Examples of coordinate compounds ""

Types of Coordinate Bonds

  • Sigma bonds
  • Pi bonds
  • Metal-ligand coordinate bonds ""

Sigma Bonds

  • Definition of sigma bonds
  • Formation of sigma bonds
  • Examples of sigma bonds ""

Pi Bonds

  • Definition of pi bonds
  • Formation of pi bonds
  • Unhybridized p orbitals
  • Examples of pi bonds ""

Metal-Ligand Coordinate Bonds

  • Definition of metal-ligand coordinate bonds
  • Formation of metal-ligand coordinate bonds
  • Examples of metal-ligand coordinate bonds ""

Hybridization

  • Definition of hybridization
  • Types of hybridization
    • sp hybridization
    • sp2 hybridization
    • sp3 hybridization
  • Examples of hybridization ""

Shapes of Coordinate Compounds

  • Linear geometry
  • Trigonal planar geometry
  • Tetrahedral geometry
  • Octahedral geometry ""

Molecular Orbital Theory

  • Introduction to molecular orbital theory
  • Concept of molecular orbitals
  • Bonding and antibonding molecular orbitals
  • Filling of molecular orbitals
  • Examples of molecular orbitals ""

Back Bonding

  • Definition of back bonding
  • Significance of back bonding
  • Examples of back bonding ""

Bond Polarity and Dipole Moment

  • Definition of bond polarity
  • Factors influencing bond polarity
  • Calculation of dipole moment
  • Examples of bond polarity and dipole moment

Coordinate Compounds - Valence Bond Theory

  • Definition of coordinate compounds
  • Introduction to valence bond theory
  • Valence bond theory principles
    • Overlapping of atomic orbitals
    • Hybridization of atomic orbitals
    • Formation of localized bonds
  • Formation of coordinate bonds
  • Examples of coordinate compounds

Types of Coordinate Bonds

  • Sigma bonds
  • Pi bonds
  • Metal-ligand coordinate bonds

Sigma Bonds

  • Definition of sigma bonds
  • Formation of sigma bonds
  • Examples of sigma bonds

Pi Bonds

  • Definition of pi bonds
  • Formation of pi bonds
  • Unhybridized p orbitals
  • Examples of pi bonds

Metal-Ligand Coordinate Bonds

  • Definition of metal-ligand coordinate bonds
  • Formation of metal-ligand coordinate bonds
  • Examples of metal-ligand coordinate bonds

Hybridization

  • Definition of hybridization
  • Types of hybridization
    • sp hybridization
    • sp2 hybridization
    • sp3 hybridization
  • Examples of hybridization

Shapes of Coordinate Compounds

  • Linear geometry
  • Trigonal planar geometry
  • Tetrahedral geometry
  • Octahedral geometry

Molecular Orbital Theory

  • Introduction to molecular orbital theory
  • Concept of molecular orbitals
  • Bonding and antibonding molecular orbitals
  • Filling of molecular orbitals
  • Examples of molecular orbitals ""

Back Bonding

  • Definition of back bonding
  • Significance of back bonding
  • Examples of back bonding ""

Bond Polarity and Dipole Moment

  • Definition of bond polarity
  • Factors influencing bond polarity
  • Calculation of dipole moment
  • Examples of bond polarity and dipole moment ""

Factors Affecting Stability of Coordinate Compounds

  • Nature of the central metal atom
  • Nature of the ligands
  • Coordination number
  • Chelation effect
  • Examples of stability factors ""

Isomerism in Coordinate Compounds

  • Definition of isomerism
  • Types of isomerism (geometric, optical, linkage)
  • Examples of isomerism in coordinate compounds ""

Coordination Complexes and Color

  • Explanation of the color of coordination compounds
  • Crystal field theory and color
  • Charge transfer and color
  • Ligand field theory and color
  • Examples of coordination complexes and color ""

Coordination Compounds in Biological Systems

  • Role of coordination compounds in biological systems
  • Examples of coordination compounds in biological systems (hemoglobin, chlorophyll)
  • Medicinal applications of coordination compounds ""

Industrial Applications of Coordinate Compounds

  • Use of coordination compounds in dyes and pigments
  • Coordination compounds in pharmaceuticals
  • Coordination compounds in catalysis
  • Examples of industrial applications of coordination compounds ""

Coordination Chemistry and Environmental Impact

  • Environmental implications of coordination compounds
  • Toxicity of certain coordination compounds
  • Water pollution caused by heavy metal complexes
  • Examples of coordination compounds and environmental impact ""

Review and Summary

  • Summary of key concepts covered
  • Reiteration of valence bond theory and molecular orbital theory
  • Importance of coordinate compounds in various fields
  • Preparation for 12th Boards chemistry exam