General Principles And Processes Of Isolation Of Metals Question 11

Question 11 - 01 February - Shift 1

Given below are two statements: one is labelled as

Assertion A and the other is labelled as Reason R

Assertion A: In an Ellingham diagram, the oxidation of carbon to carbon monoxide shows a negative slope with respect to temperature.

Reason R: CO tends to get decomposed at higher temperature.

In the light of the above statements, choose the correct answer from the options given below

(1) Both A and R are correct and R is the correct explanation of $A$

(2) A is not correct but $R$ is correct

(3) Both A and R are correct but R is NOT the correct explanation of $A$

(4) A is correct but R is not correct

Show Answer

Answer: (4)

Solution:

Formula: Ellingham Diagram

$2 C(s)+O_2(g) \to 2 CO(g)$

$\Delta_r S^{o}$ is +ve, $\Delta_r G^{o}=\Delta_r H^{o}-T \Delta_r S^{\circ}$; thus slope is

negative

As temperature increases $\Delta_r G^{0}$ becomes more

negative thus it has lower tendency to get

decomposed.