NEET Solved Paper 2018 Question 16

Question: The compound $ {C_7}{H_8} $ undergoes the following reactions $ :{C_7}{H_8}\xrightarrow{3Cl _2/\Delta }A\xrightarrow{Br _2/Fe}B\xrightarrow{Zn/HCl}C $ . The product ‘C’ is [NEET - 2018]

Options:

A) 3-bromo-2, 4, 6-trichlorotoluene

B) o-bromotoluene

C) m-bromotoluene

D) p-bromotoluene

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Answer:

Correct Answer: C

Solution:

  • Benzochloride in presence of Br2/Fe give an electrophilic substitution reaction.Br2/Fe generates a free radical Br- which attacks on the meta position.m-bromo benzochloride is obtained as a product of the second step.So, B will be m-bromo benzochloride.