NEET Solved Paper 2017 Question 37

Question: Extraction of gold and silver involves leaching with $ C{N^{-}} $ ion. Silver is later recovered by

Options:

A) Displacement with Zn

B) Liquation

C) Distillation

D) Zone refining

Show Answer

Answer:

Correct Answer: A

Solution:

  • Zn being more reactive than Ag and Au, displaces them. From Native ore, $ 4Ag+8NaCN+2H _2O+O _2\xrightarrow{Leaching} $ $ \underset{\begin{smallmatrix} ,Souble \\ Sodium, \\ ,dicyanoargen,late,\text{(I)} \end{smallmatrix}}{\mathop{4Na[Ag{{(CN)}_2}]}},+4NaOH $ $ 2Na[Ag{{(CN)}_2}]+Zn\xrightarrow{Displaceement} $ $ Na _2[Zn{{(CN)}_4}]+2Ag\downarrow $