NEET Solved Paper 2014 Question 17

Question: 1.0 g of magnesium is burnt with 0.56 g $ O _2 $ in a closed verssel. Which reactant is left in excess and how much? $ (At.wt.Mg=24;O=16) $ [AIPMT 2014]

Options:

A) $ Mg,0.16g $

B) $ O _2.0.16g $

C) $ Mg,0.44g $

D) $ O _2,0.28g $

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Answer:

Correct Answer: A

Solution:

  • The balanced chemical equation is $ \underset{\begin{smallmatrix} \\ \\ 24g \end{smallmatrix}}{\mathop{Mg}},+\underset{\begin{smallmatrix} \\ 16g \end{smallmatrix}}{\mathop{\frac{1}{2}O _2}},\xrightarrow{,}\underset{\begin{smallmatrix} \\ \\ 40g \end{smallmatrix}}{\mathop{MgO}}, $ From the above equation, it is clear that, 24 g Mg reacts with 16 g $ O _2. $ Thus, 1.0 g Mg reacts with $ \frac{16}{24}\times 0.67g,O _2=0.67g,O _2. $ But only 0.56 g $ O _2 $ is available which less than 0.67 g is. Thus, $ O _2 $ is the limiting reagent. Further, 16 g $ O _2 $ reacts with Mg 24 g.
    $ \therefore $ 0.56 g $ O _2 $ will react with Mg $ =\frac{24}{16}\times 0.56=0.84g $
    $ \therefore $ Amount of Mg left unreacted = 1.0 - 0.84g Mg = 0.16g Mg Hence, Mg is present in excess and 0.16 g Mg is left behind unreacted.