States of Matter 1 Question 65

65. If the value of Avogadro number is $6.023 \times 10^{23} \mathrm{~mol}^{-1}$ and the value of Boltzmann constant is $1.380 \times 10^{-23} \mathrm{JK}^{-1}$, then the number of significant digits in the calculated value of the universal gas constant is

(2014 Adv.)

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Answer:

Correct Answer: 65. (4)

Solution:

  1. PLAN This problem can be solved by using the concept involved in calculation of significant figure.

Universal gas constant, $R=k N_{A}$

where, $\quad k=$ Boltzmann constant

and $\quad N_{A}=$ Avogadro’s number

$$ \begin{aligned} \therefore \quad R & =1.380 \times 10^{-23} \times 6.023 \times 10^{23} \mathrm{~J} / \mathrm{Kmol} \ & =8.31174 \cong 8.312 \end{aligned} $$

Since, $k$ and $N_{A}$ both have four significant figures, so the value of $R$ is also rounded off upto 4 significant figures.

[When number is rounded off, the number of significant figure is reduced, the last digit is increased by 1 if following digits $\geq 5$ and is left as such if following digits is $\leq 4$.]

Hence, correct integer is (4).